物理化学学报 >> 1996, Vol. 12 >> Issue (05): 472-475.doi: 10.3866/PKU.WHXB19960518

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Pt/HM,Pd/HM催化剂上NO-TPSR和CO-NO反应

罗孟飞,朱波,陈敏,丁云杰,袁贤鑫   

  1. 杭州大学催化研究所，杭州 310028
  • 收稿日期:1995-09-05 修回日期:1995-11-26 发布日期:1996-05-15
  • 通讯作者:

The CO-NO Reaction and the NO-TPSR on Pt/HM and Pd/HM Catalysts

Luo Meng-Fei,Zhu Bo,Chen Min,Ding Yun-Jie,Yuan Xian-Xin   

  1. Institute of Catalysis,Hangzhou University,Hangzhou 310028
  • Received:1995-09-05 Revised:1995-11-26 Published:1996-05-15
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关键词: NO-TPSR, CO-NO催化反应, Pt, Pd

Abstract:

NO-TPSR and CO-NO catalytic reaction on Pt/HM and Pd/HM were studied. There are three kinds of NO adsoption sites. The lower temperature adsoption site is attributed to the metal Pt or Pd, and the two higher temperature adsoption sites are attributed to the basic sites on HM surface. The adsorbed NO undergoes extensive decomposition to form N2、N2O and O2 during NO thermal desorption on all catalysts studied. The desorption of N2、N2O and NO on Pt/HM catalyst is easier than that on Pd/HM catalyst. Pt/HM catalytic activity for CO-NO reaction is higher than Pd/HM's, which is consistant with NO decomposition ability of the catalyst. The dissociation of NO on catalyst is the rate determing step of CO-NO reaction.

Key words: NO-TPSR, CO-NO catalytic reaction, Pt, Pd