物理化学学报 >> 1999, Vol. 15 >> Issue (03): 241-246.doi: 10.3866/PKU.WHXB19990309

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手性金属簇合物的合成、结构表征及其反应

丁二润, 吴树林, 李庆山, 殷元骐   

  1. 中国科学院兰州化学研究所 羟基合成与选择氧化国家重点实验室，兰州 730000
  • 收稿日期:1998-05-04 修回日期:1998-10-05 发布日期:1999-03-15
  • 通讯作者:

Synthesis,Structural Characterization and Reaction of the Chiral Clusters

Ding Er-Run, Wu Shu-Lin, Li Qing-Shan, Yin Yuan-Qi   

  1. State Key Laboratory for Oxo Synthesis and Selective Oxidation,Lanzhou Institute of Chemical Physics,Chinese Academy of Sciences,Lanzhou 730000
  • Received:1998-05-04 Revised:1998-10-05 Published:1999-03-15
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摘要：

用潜手性羰基簇合物 ( μ3-S)RuCo2 (CO) 9( 1 )与阴离子金属交换试剂Na[M (CO) 3C5 H4C(O)R][R =H ,CH3,C6 H5 ,C6 H4C(O)OCH3;M =Mo ,W ]在四氢呋喃中回流反应 ,生成一系列新的由四个不同原子组成的不对称四面体簇合物 ( μ3-S)RuCoM (CO ) 8CpCOR .研究了簇合物 ( μ3-S)RuCoMo(CO) 8CpCOCH3的还原反应 .对合成的所有化合物进行了IR、1HNMR、C/H元素分析 ,测定了簇合物( μ3-S)RuCoMo(CO) 8CpCOC6H5 的单晶结构 .

关键词: 过渡金属, 簇合物, 晶体结构

Abstract:

Several chiral clusters RuCoMo(μ-3 S)(CO) 8C 5H 4C(O)R were synthesized by the thermal reaction of the precursor (μ-3 S)RuCo2(CO) 9 with functionally substituted cyclopentadienyl tricarbonyl metal complex anions [M(CO) 3(η5-C5H4)C(O)R] -(R=H,CH3,C6H5,C 6H 4C(O)OCH 3;M=Mo,W)in THF. All of these clusters were characterized by C/H elemental analysis, IR and 1H NMR. Crystal structure of the cluster (μ-3 S)RuCoMo(CO)8CpCOC6H5 has also been solved by single crystal X ray diffraction.

Key words: Transition metal, Cluster, Crystal structure