锂硫二次电池正极研究进展

doi:10.3866/PKU.WHXB20110345

摘要/Abstract

摘要：

综述了锂硫电池中硫基正极材料的制备方法、结构特征以及电化学性能. 简述了单质硫正极材料, 重点探讨了有机硫化物、碳/硫复合材料、聚合物/硫复合材料的结构设计、材料制备、反应机理以及充放电特性, 并对其中存在的问题进行了分析, 还介绍了硫化锂正极材料. 最后对硫基正极的进一步发展, 以及锂硫电池的商业化应用进行了展望.

关键词: 锂硫二次电池, 正极, 硫基复合材料, 循环性能

Abstract:

The preparation, characteristics and electrochemical performances of the sulfur-based cathode materials in lithium/sulfur batteries are reviewed in this paper. The elemental sulfur cathode material is briefly introduced. The structural designs, preparation processes, reaction mechanisms, and charge/discharge properties of organic sulfide, sulfur-porous carbon and sulfur-polymer composites as cathode materials are systematically discussed and problems associated with these materials are also analyzed. In addition, the research and application of lithium sulfides as cathode materials are also outlined. Finally, the further development of sulfur-based cathode materials and the commercialization of lithium/sulfur batteries are discussed.

Key words: Lithium-sulfur rechargeable battery, Cathode, Sulfur-based composite material, Cycle performance

姚真东, 魏巍, 王久林, 杨军, 努丽燕娜. 锂硫二次电池正极研究进展[J]. 物理化学学报, 2011, 27(05), 1005-1016. doi: 10.3866/PKU.WHXB20110345

YAO Zhen-Dong, WEI Wei, WANG Jiu-Lin, YANG Jun, NULI Yan-Na. Review of Sulfur-Based Cathodes for High Performance Lithium Rechargeable Batteries[J]. Acta Phys. -Chim. Sin. 2011, 27(05), 1005-1016. doi: 10.3866/PKU.WHXB20110345

链接本文: https://www.whxb.pku.edu.cn/CN/10.3866/PKU.WHXB20110345

https://www.whxb.pku.edu.cn/CN/Y2011/V27/I05/1005

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