微波辅助裂解离子液体制备硫氮共掺杂多孔碳材料

doi:10.3866/PKU.WHXB201705083

物理化学学报 >> 2017, Vol. 33 >> Issue (9): 1915-1922.doi: 10.3866/PKU.WHXB201705083

论文上一篇

微波辅助裂解离子液体制备硫氮共掺杂多孔碳材料

蒙延双^1,³,王琛¹,王磊¹,王功瑞¹,夏军¹,朱福良^1,^3,*(),ZHANG Yue^2,*()

¹ 兰州理工大学材料科学与工程学院,兰州730050
² Department of Mechanical and Industrial Engineering, Texas A & M University-Kingsville, Kingsville, Texas 78363, USA
³ 省部共建有色金属先进加工与再利用国家重点实验室,兰州730050

收稿日期:2017-03-22 发布日期:2017-07-05
通讯作者: 朱福良,ZHANG Yue E-mail:chzfl@126.com;yue.zhang@tamuk.edu
基金资助:
国家自然科学基金(51364024);国家自然科学基金(51404124);甘肃省自然科学基金(1506RJZA100);甘肃省基础研究创新群体计划项目(1606RJIA322)

Efficient Synthesis of Sulfur and Nitrogen Co-Doped Porous Carbon by Microwave-Assisted Pyrolysis of Ionic Liquid

Yan-Shuang MENG^1,³,Chen WANG¹,Lei WANG¹,Gong-Rui WANG¹,Jun XIA¹,Fu-Liang ZHU^1,^3,*(),Yue ZHANG^2,*()

¹ School of Materials Science and Engineering, Lanzhou University of Technology, Lanzhou 730050, P. R. China
² Department of Mechanical and Industrial Engineering, Texas A & M University-Kingsville, Kingsville, Texas 78363, USA
³ State Key Laboratory of Advanced Processing and Recycling of Non-ferrous Metals, Lanzhou 730050, P. R. China

Received:2017-03-22 Published:2017-07-05
Contact: Fu-Liang ZHU,Yue ZHANG E-mail:chzfl@126.com;yue.zhang@tamuk.edu
Supported by:
the National Natural Science Foundation of China(51364024);the National Natural Science Foundation of China(51404124);Natural Science Foundation of Gansu Province, China(1506RJZA100);the Foundation for Innovation Groups of Basic Research in Gansu Province, China(1606RJIA322)

摘要/Abstract

摘要：

采用一步微波辅助裂解离子液体法制备了硫氮共掺杂多孔碳材料。用傅里叶变换红外（FT-IR）光谱，拉曼光谱，X射线衍射（XRD），电子显微镜和X射线光电子能谱（XPS）等检测手段对裂解产物的结构和形貌进行了表征。对微波辐照下离子液体1-乙基-3-甲基咪唑双三氟甲磺酰亚胺盐（EMImNTf₂）的裂解机理进行了分析。结果表明，微波辐照能够促进EMImNTf₂的裂解，使其在320 ℃下裂解得到硫氮共掺杂的多孔碳材料。离子液体EMImNTf₂的阳离子作为多孔碳材料骨架的前驱体，而阴离子作为硫源和造孔剂。制备的硫氮共掺杂多孔碳材料具有含缺陷的石墨结构。石墨碳基体中氮和硫的原子百分含量分别为12.84%和1.07%，其中N原子主要取代C成为活性点，而S原子主要存在于边界和缺陷处。

关键词: 硫氮共掺杂, 多孔碳, 微波, 裂解, 离子液体

Abstract:

Sulfur and nitrogen co-doped porous carbon (SNDPC) was successfully synthesized using one-step microwave-assisted pyrolysis of ionic liquid. The structure and morphology of the pyrolysis products were characterized by Fourier-transform infrared (FT-IR) spectroscopy, Raman spectroscopy, X-ray diffraction (XRD), electron microscopy, and X-ray photoelectron spectroscopy (XPS). The pyrolysis mechanism of the ionic liquid 1-ethyl-3-methylimidazolium bis((trifluoromethyl)sulfonyl)imide (EMImNTf₂) under microwave irradiation was discussed. Microwave irradiation was found to accelerate the pyrolysis of EMImNTf₂. The cation of EMImNTf₂ works as the precursor of the carbon backbone of the porous carbon, while the anion acts as sulfur source and porosity-directing regulator. The SNDPC was obtained at 320 ℃ and exhibited graphitic structure with numerous surface defects. The atomic percentages of N and S in SNDPC were 12.84% and 1.07%, respectively. The N atoms mainly substitute the C sites in the graphitic carbon matrix, whereas the S atoms mainly bond to the ledges and defects of the carbon matrix.

Key words: Sulfur and nitrogen co-doped, Porous carbon, Microwave, Pyrolysis, Ionic liquid

蒙延双,王琛,王磊,王功瑞,夏军,朱福良,ZHANG Yue. 微波辅助裂解离子液体制备硫氮共掺杂多孔碳材料[J]. 物理化学学报, 2017, 33(9), 1915-1922. doi: 10.3866/PKU.WHXB201705083

Yan-Shuang MENG,Chen WANG,Lei WANG,Gong-Rui WANG,Jun XIA,Fu-Liang ZHU,Yue ZHANG. Efficient Synthesis of Sulfur and Nitrogen Co-Doped Porous Carbon by Microwave-Assisted Pyrolysis of Ionic Liquid[J]. Acta Phys. -Chim. Sin. 2017, 33(9), 1915-1922. doi: 10.3866/PKU.WHXB201705083

链接本文: https://www.whxb.pku.edu.cn/CN/10.3866/PKU.WHXB201705083

https://www.whxb.pku.edu.cn/CN/Y2017/V33/I9/1915

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微波辅助裂解离子液体制备硫氮共掺杂多孔碳材料

Efficient Synthesis of Sulfur and Nitrogen Co-Doped Porous Carbon by Microwave-Assisted Pyrolysis of Ionic Liquid

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