静电诱导缺陷极化增强型PBA/MXene异质结构的双耦合界面以提升电磁波吸收性能

doi:10.1016/j.actphy.2026.100312

摘要/Abstract

摘要：

普鲁士蓝类似物(PBAs)因其可调控的配位框架和本征多孔性备受关注，但其结构稳定性不足与衰减能力有限制约了PBA衍生电磁波吸收体的性能。金属-碳异质结构体系可显著改善这些缺陷，但精确构建多组分异质界面并调控磁畴行为仍具挑战性。在此，我们提出一种静电场自辅助策略，成功构建双金属PBA衍生的多类型碳包覆/MXene (NiCo@C@C/MXene)异质结构，其精确设计的多组分界面形成静电诱导双耦合界面网络，成为增强介电损耗的核心机制。MXene纳米片和聚多巴胺(PDA)涂层协同强化PBA衍生碳基体，构建多维导电通路，而多类型碳基体、缺陷孔隙和磁性纳米颗粒共同增强了界面极化和磁损耗。这种协同效应实现了优化的阻抗匹配、强衰减特性和宽频吸收性能，使该材料在仅1.57 mm的超薄厚度下实现了−58.51 dB的最小反射损耗(RL)和5.44 GHz的有效吸收带宽(EAB)。雷达散射截面模拟进一步揭示了强化电磁波耗散的磁畴耦合网络。该研究为突破PBA材料本征局限和界面工程难题提供了新思路，为下一代高性能电磁波衰减材料开辟了路径。

关键词: 普鲁士蓝类似物, 电磁波吸收, 静电自组装, 异质结构, 协同效应

Abstract:

Prussian blue analogues (PBAs) offer tunable coordination frameworks and intrinsic porosity, yet their limited structural robustness and attenuation capability restrict the performance of PBA-derived electromagnetic wave (EMW) absorbers. These drawbacks can be substantially mitigated in metal-carbon heterostructure systems, yet achieving well-defined multi-component heterogeneous interfaces and controllable magnetic-domain behavior remains challenging. Here, we propose an electrostatic-field self-assisted strategy to construct bimetallic PBA-derived multi-type carbon-encapsulated/MXene (NiCo@C@C/MXene) heterostructures with precisely engineered multi-component interfaces, which create a rich landscape of electrostatically induced dual-coupled interfaces acting as a core mechanism for enhancing dielectric loss. MXene nanosheets and PDA coating reinforce the PBA-derived carbon matrix and form multidimensional conductive pathways, while multi-type carbon matrix, defect porosity, and magnetic nanoparticles collectively enhance interfacial polarization and magnetic loss. The resulting synergy yields optimized impedance matching, strong attenuation, and broadband absorption, enabling the material to achieve a minimum reflection loss (RL) of −58.51 dB and an effective absorption bandwidth (EAB) of 5.44 GHz at an ultrathin thickness of only 1.57 mm. Radar cross-section simulations further reveal domain-coupling networks that intensify EMW dissipation. This work establishes a concise route to address intrinsic PBA limitations and interface-engineering challenges, enabling next-generation high-performance EMW attenuation materials.

Key words: Prussian blue analogues, Electromagnetic wave absorption, Electrostatic self-assembly, Heterostructure, Synergistic effect

贾志卿, 宫新菊, 兰笛, 孙环环, 刘雨, 高玉萍, 郭思瑶. 静电诱导缺陷极化增强型PBA/MXene异质结构的双耦合界面以提升电磁波吸收性能[J]. 物理化学学报, 2026, 42(8), 100312. doi: 10.1016/j.actphy.2026.100312

Zhiqing Jia, Xinju Gong, Di Lan, Huanhuan Sun, Yu Liu, Yuping Gao, Siyao Guo. Electrostatically induced dual-coupled interfaces of defect polarization enhanced PBA/MXene heterostructures for boosting electromagnetic wave absorption[J]. Acta Phys. -Chim. Sin. 2026, 42(8), 100312. doi: 10.1016/j.actphy.2026.100312

链接本文: https://www.whxb.pku.edu.cn/CN/10.1016/j.actphy.2026.100312

https://www.whxb.pku.edu.cn/CN/Y2026/V42/I8/100312

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参考文献 77

1	H. Jian, Q. Du, Q. Men, L. Guan, R. Li, B. Fan, X. Zhang, X. Guo, B. Zhao, R. Zhang. J. Mater. Sci. Technol. 2022, 109, 105. doi: 10.1016/j.jmst.2021.07.060
2	J. Zhou, Y. Sui, N. Wu, M. Han, J. Liu, W. Liu, Z. Zeng, J. Liu. Small 2024, 20, 2405968. doi: 10.1002/smll.202405968
3	Q. Qu, H. Wang, Q. Dong, Y. He. Diam. Relat. Mat. 2023, 132, 109620. doi: 10.1016/j.diamond.2022.109620
4	L. Jiang, X. Chen, S. Zhang, H. Wang, X. Tian, R. Li, J. Fan, G. Gou. Carbon 2024, 229, 119553. doi: 10.1016/j.carbon.2024.119553
5	Y. Qiu, Y. Lin, H. Yang, L. Wang, M. Wang, B. Wen. Chem. Eng. J. 2020, 383, 123207. doi: 10.1016/j.cej.2019.123207
6	Y. Bai, F. Qin, Y. Lu. Chem. Eng. J. 2022, 429, 132393. doi: 10.1016/j.cej.2021.132393
7	Z. Xiang, Y. Wang, X. Yin, Q. He. Chem. Eng. J. 2023, 451, 138742. doi: 10.1016/j.cej.2022.138742
8	C. Zheng, W. Qi, M. Ning, L. Xiang, T. Liu, Y. Li, G. Lv, Q. Wu, Q. Man, B. Shen. J. Alloy. Compd. 2024, 983, 173784. doi: 10.1016/j.jallcom.2024.173784
9	W. Li, C. Han, G. Cheng, S. Chou, H. Liu, S. Dou. Small 2019, 15, 1900470. doi: 10.1002/smll.201900470
10	Q. Liang, M. He, B. Zhan, H. Guo, X. Qi, Y. Qu, Y. Zhang, W. Zhong, J. Gu. Nano-Micro Lett. 2025, 17, 167. doi: 10.1007/s40820-024-01626-8
11	B. Wang, F. Huang, P. Zhang, F. Liu, S. Li, H. Zhang. Carbon 2024, 230, 119633. doi: 10.1016/j.carbon.2024.119633
12	S. Xu, Z. Yao, X. Zhang, J. Yuan, C. Rong, Z. Xiong, X. Zhu, Y. Yu, H. Yu, S. Kang, et al.. Mater. Res. Bull. 2023, 165, 112284. doi: 10.1016/j.materresbull.2023.112284
13	S. Wei, T. Chen, Z. Shi, S. Chen. J. Colloid Interface Sci. 2022, 610, 395. doi: 10.1016/j.jcis.2021.12.051
14	X. Shui, H. Ma, Y. Zhang, T. Zeng, J. Yang, Z. Wu, X. Zhang, N. Yang. Chem. Eng. J. 2024, 500, 156714. doi: 10.1016/j.cej.2024.156714
15	Y. Yang, S. Xu, Q. Huang, Q. Ren, S. Chen, Z. Jin, Y. Ge, W. Liao, W. Xu, H. Xu, et al.. Mater. Res. Bull. 2024, 178, 112907. doi: 10.1016/j.materresbull.2024.112907
16	Z. Wang, Z. Cheng, C. Fang, X. Hou, L. Xie. Compos. Pt. A-Appl. Sci. Manuf. 2020, 136, 105956. doi: 10.1016/j.compositesa.2020.105956
17	Q. Li, K. Nan, W. Wang, H. Zheng, K. He, Y. Wang. J. Colloid Interface Sci. 2024, 662, 796. doi: 10.1016/j.jcis.2024.02.125
18	G. Cui, X. Sun, G. Zhang, Z. Zhang, H. Liu, J. Gu, G. Gu. Mater. Lett. 2019, 252, 8. doi: 10.1016/j.matlet.2019.05.053
19	X. Zeng, C. Zhao, Y. Yin, T. Nie, N. Xie, R. Yu, G. Stucky. Carbon 2022, 193, 26. doi: 10.1016/j.carbon.2022.03.029
20	H. Guan, J. Zong, M. Wang, H. Zhai, J. Yuan, M. Cao. Carbon 2024, 226, 119239. doi: 10.1016/j.carbon.2024.119239
21	X. Yu, L. Yu, B. Wu, X. Lou. Angew. Chem. -Int. Edit. 2015, 54, 5331. doi: 10.1002/anie.201500267
22	J. Chen, B. Lei, Y. Hou, J. Lei, P. Chen, Z. Li, D. Zhao. Carbon 2024, 224, 119081. doi: 10.1016/j.carbon.2024.119081
23	Y. Bao, S. Guo, Y. Li, Z. Jia, H. Guan, D. Lei, J. Chen, B. Zhong, Z. Li. ACS Appl. Electron. Mater. 2023, 5, 227. doi: 10.1021/acsaelm.2c01271
24	S. Mao, R. Miao, D. Lan, S. Zhang, J. Zhou, X. Liu, S. Du, Z. Zhao, G. Wu. Acta Phys. -Chim. Sin. 2026, 42, 100279. doi: 10.1016/j.actphy.2026.100279
25	X. Liang, Q. Xuan, H. Li, P. Ding, Y. Zhang, M. Koo, C. Liang, S. Yang, P. Zhao, D. Zhang, et al.. Chem. Eng. J. 2025, 523, 168409. doi: 10.1016/j.cej.2025.168409
26	L. Cui, Y. Wang, X. Han, P. Xu, F. Wang, D. Liu, H. Zhao, Y. Du. Carbon 2021, 174, 673. doi: 10.1016/j.carbon.2020.10.070
27	S. Fang, D. Huang, R. Lv, Y. Bai, Z. Huang, J. Gu, F. Kang. RSC Adv. 2017, 7, 25773. doi: 10.1039/c7ra03215c
28	Y. Yue, Y. Wang, X. Xu, C. Wang, Z. Yao, D. Liu. Ceram. Int. 2022, 48, 6338. doi: 10.1016/j.ceramint.2021.11.176
29	J. Guo, Y. Sun, X. Li, G. Zhao, M. Helal, D. Pan, H. Thabet, W. Wu, W. Abdul, S. El-Bahy, et al.. Adv. Mater. Interfaces 2025, 12, 2500075. doi: 10.1002/admi.202500075
30	L. Yang, Y. Wang, Z. Lu, R. Cheng, N. Wang, Y. Li. Carbon 2023, 205, 411. doi: 10.1016/j.carbon.2023.01.057
31	X. Ren, Z. Jia, Z. Gao, S. Zhang, Y. Zhang, D. Lan, G. Wu. Adv. Funct. Mater. 2025, e24264. doi: 10.1002/adfm.202524264
32	T. Hu, D. Lan, J. Wang, X. Zhong, G. Bu, P. Yin. Carbon 2025, 232, 119798. doi: 10.1016/j.carbon.2024.119798
33	M. Shi, Z. Jia, S. Xu, Z. Gao, G. Wu. Adv. Funct. Mater. 2026, e74648. doi: 10.1002/adfm.74648
34	X. Zhu, X. Qian, M. Hao, Y. Zhang, Z. Zhang, S. Li, H. Wu. J. Alloy. Compd. 2024, 989, 174440. doi: 10.1016/j.jallcom.2024.174440
35	P. Yi, X. Zhang, L. Jin, P. Chen, J. Tao, J. Zhou, Z. Yao. Chem. Eng. J. 2022, 430, 132879. doi: 10.1016/j.cej.2021.132879
36	S. Deng, X. Xu, C. Fan, Q. He, Y. Wang. Colloid Surf. A-Physicochem. Eng. Asp. 2025, 727, 138430. doi: 10.1016/j.colsurfa.2025.138430
37	J. Wen, D. Lan, Y. Wang, L. Ren, A. Feng, Z. Jia, G. Wu, Int. J. Miner.. Metall. Mater. 2024, 31, 1701. doi: 10.1007/s12613-024-2881-0
38	Y. Pan, K. Yu, D. Lan, Z. Zhang, Z. Chen. Carbon 2025, 245, 120824. doi: 10.1016/j.carbon.2025.120824
39	J. Xiong, Z. Xiang, J. Zhao, L. Yu, E. Cui, B. Deng, Z. Liu, R. Liu, W. Lu. Carbon 2019, 154, 391. doi: 10.1016/j.carbon.2019.07.096
40	X. Zeng, C. Zhao, T. Nie, Z. Shen, R. Yu, G. Stucky. Mater. Today Phys. 2022, 28, 100888. doi: 10.1016/j.mtphys.2022.100888
41	J. He, J. Li, J. Zhang, P. Yi, X. Sun, G. Han, X. Li, R. Zhang, X. Liu, R. Yu. Carbon 2023, 214, 118266. doi: 10.1016/j.carbon.2023.118266
42	Y. Jin, C. Fan, Q. Zhang, Q. He, Y. Wang. Inorg. Chem. Front. 2025, 12, 7590. doi: 10.1039/d5qi01376c
43	T. Liu, D. Lan, S. Zhang, P. Wang, S. Zhang, X. Zhao, X. Liang, Z. Zhao. Acta Phys. -Chim. Sin. 2026, 100289. doi: 10.1016/j.actphy.2026.100289
44	Y. Cui, Z. Liu, Y. Zhang, P. Liu, M. Ahmad, Q. Zhang, B. Zhang. Carbon 2021, 181, 58. doi: 10.1016/j.carbon.2021.05.022
45	Z. Wang, Y. Chen, M. Yao, J. Dong, Q. Zhang, L. Zhang, X. Zhao. J. Power Sources 2020, 448, 227398. doi: 10.1016/j.jpowsour.2019.227398
46	L. Hu, M. Li, X. Wei, H. Wang, Y. Wu, J. Wen, W. Gu, C. Zhu. Chem. Eng. J. 2020, 398, 125605. doi: 10.1016/j.cej.2020.125605
47	Y. Bao, S. Guo, W. Wang, X. Qi, Z. Jia, H. Guan. Chem. Eng. J. 2023, 473, 145409. doi: 10.1016/j.cej.2023.145409
48	X. Zhu, H. Qiu, P. Chen, G. Chen, W. Min. Carbon 2021, 176, 530. doi: 10.1016/j.carbon.2021.02.044
49	Y. Bao, W. Wang, Y. Liu, Z. Yue, S. Guo. Appl. Surf. Sci. 2025, 680, 161393. doi: 10.1016/j.apsusc.2024.161393
50	Q. Li, Z. Gao, W. Zhou, S. Yang, Z. Jia, G. Wu. Nano Res. 2026, 19, 94908525. doi: 10.26599/NR.2026.94908525
51	M. Qin, L. Zhang, H. Wu. Adv. Sci. 2022, 9, 2105553. doi: 10.1002/advs.202105553
52	S. Wu, C. Wang, Y. Tang, J. Jiang, H. Jiang, X. Xu, B. Cui, Y. Jiang, Y. Wang. Adv. Fiber Mater. 2024, 6, 430. doi: 10.1007/s42765-023-00362-9
53	L. Yao, J. Dang, J. Xiao, Y. Chen, J. Ding, Y. Qu, Q. Peng, X. Qi, W. Zhong. J. Mater. Sci. Technol. 2026, 240, 190. doi: 10.1016/j.jmst.2025.04.011
54	B. Du, M. Cai, X. Wang, J. Qian, C. He, A. Shui. J. Adv. Ceram. 2021, 10, 832. doi: 10.1007/s40145-021-0476-z
55	L. Yang, F. Li, Y. Duan, H. Wang. Compos. Commun. 2025, 53, 102173. doi: 10.1016/j.coco.2024.102173
56	X. Zhou, J. Wen, Z. Wang, X. Ma, H. Wu. J. Colloid Interface Sci. 2021, 602, 834. doi: 10.1016/j.jcis.2021.06.083
57	X. Ren, D. Lan, Z. Gao, S. Zhang, Y. Zhang, M. He, Z. Jia, G. Wu. J. Mater. Sci. Technol. 2026, 255, 236. doi: 10.1016/j.jmst.2025.09.001
58	Y. Lei, Q. He, Y. Wang, C. Fan, X. Yin, C. Wang, L. Liu. ACS Sustain. Chem. Eng. 2025, 13, 16679. doi: 10.1021/acssuschemeng.5c07718
59	L. Zhou, H. Wang, Y. Guo, M. Bai, N. Leng, X. Sun, G. Wang, J.. Gu, Sci. China-Mater. 2026, 1. doi: 10.1007/s40843-025-3903-4
60	J. Wang, B. Cai, B. Sun, Z. Hou, S. Yang, Q. Yang, P. Zhao, W. Li, Y. Zhang, G. Wang. Acta Phys. -Chim. Sin. 2026, 100271. doi: 10.1016/j.actphy.2026.100271
61	P. Li, D. Xiang, Q. He, C. Fan, Y. Wang, X. Yin. J. Colloid Interface Sci. 2026, 702, 138997. doi: 10.1016/j.jcis.2025.138997
62	S. Masoudpanah. J. Mater. Res. Technol-JMRT 2022, 20, 3264. doi: 10.1016/j.jmrt.2022.08.042
63	H. Wang, H. Ren, C. Jing, J. Li, Q. Zhou, F. Meng. Compos. Sci. Technol. 2021, 204, 108630. doi: 10.1016/j.compscitech.2020.108630
64	M. Wu, L. Rao, Y. Li, Z. Ji, L. Liu, P. Wang, G. Ying. J. Alloy. Compd. 2024, 971, 172552. doi: 10.1016/j.jallcom.2023.172552
65	M. Gao, S. Wang, Z. Wang, S. Wang, Y. Sun, Q. Li, S. Lei, Q. Li, Z. Zhang, X. Ma, et al.. Chem. Phys. 2024, 587, 112415. doi: 10.1016/j.chemphys.2024.112415
66	B. Quan, X. Liang, G. Ji, Y. Cheng, W. Liu, J. Ma, Y. Zhang, D. Li, G. Xu. J. Alloy. Compd. 2017, 728, 1065. doi: 10.1016/j.jallcom.2017.09.082
67	X. Zhang, Y. Dong, F. Pan, Z. Xiang, X. Zhu, W. Lu. Carbon 2021, 177, 332. doi: 10.1016/j.carbon.2021.02.092
68	H. Wang, F. Meng, F. Huang, C. Jing, Y. Li, W. Wei, Z. Zhou. ACS Appl. Mater. Interfaces 2019, 11, 12142. doi: 10.1021/acsami.9b01122
69	F. Wang, W. Gu, J. Chen, Q. Huang, M. Han, G. Wang, G. Ji. J. Mater. Sci. Technol. 2022, 105, 92. doi: 10.1016/j.jmst.2021.06.058
70	B. Liang, Y. Zhao, S. Wang, S. Huang, F. Zhou, C. Zhang, Y. Wang, X. Guo. Acta Phys. -Chim. Sin. 2026, 100285. doi: 10.1016/j.actphy.2026.100285
71	X. Zhang, J. Qiao, Y. Jiang, F. Wang, X. Tian, Z. Wang, L. Wu, W. Liu, J. Liu. Nano-Micro Lett. 2021, 13, 135. doi: 10.1007/s40820-021-00658-8
72	G. Li, R. Tan, B. Gao, Y. Zhou, C. Zhang, P. Chen, X. Wang. Carbon 2024, 228, 119315. doi: 10.1016/j.carbon.2024.119315
73	W. Yan, J. Luo, Y. Li, M. Liu, Y. Wu, Z. Dai, X. Li. Carbon 2024, 228, 119338. doi: 10.1016/j.carbon.2024.119338
74	S. Lv, H. Luo, Z. Wang, J. Yu, Y. Cheng, F. Chen, X. Li. Carbon 2024, 218, 118668. doi: 10.1016/j.carbon.2023.118668
75	J. Zhu, P. Liao, S. Xu, W. Ling, X. Zhang, J. Yuan, C. Rong, X. Liu, Z. Xiong. Surf. Interfaces 2024, 55, 105389. doi: 10.1016/j.surfin.2024.105389
76	L. Han, H. Yang, Z. Cai, Y. Lin. Carbon 2025, 232, 119817. doi: 10.1016/j.carbon.2024.119817
77	J. Xiao, B. Wen, J. Li, X. Liu, S. Xue, Z. Wei, S. Yang, G. Yang, S. Ding. J. Alloy. Compd. 2024, 1008, 176595. doi: 10.1016/j.jallcom.2024.176595

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