花瓣状WS2/MnFe2O4/GNs复合材料展现出高效电磁波吸收性能

doi:10.1016/j.actphy.2026.100273

物理化学学报 >> 2026, Vol. 42 >> Issue (9): 100273.doi: 10.1016/j.actphy.2026.100273

花瓣状WS₂/MnFe₂O₄/GNs复合材料展现出高效电磁波吸收性能

朱耿素²^,³, 马媛媛², 孙承志², 李梦婷², 王春雨¹^,²^,*(), 钟博²^,*(), 夏龙²^,*()

¹ 哈尔滨工业大学(威海)材料结构精密焊接与连接全国重点实验室, 山东威海 264209
² 哈尔滨工业大学(威海)材料科学与工程学院, 山东威海 264209
³ 西北工业大学化学与化工学院, 陕西西安 710072

收稿日期:2026-01-25 修回日期:2026-02-26 录用日期:2026-03-01 发布日期:2026-07-03
通讯作者: Email: wcyadam@126.com (王春雨)zhongbo@hit.edu.cn (钟博)xialong@hit.edu.cn (夏龙)

Preparation and absorption properties of petal-clustered WS₂/MnFe₂/O₄/GNs composite materials

Gengsu Zhu²^,³, Yuanyuan Ma², Chengzhi Sun², Mengting Li², Chunyu Wang¹^,²^,*(), Bo Zhong²^,*(), Long Xia²^,*()

¹ State Key Laboratory of Precision Welding & Joining of Materials and Structures, Harbin Institute of Technology (Weihai), Weihai 264209, Shandong Province, China
² School of Materials Science and Engineering, Harbin Institute of Technology (Weihai), Weihai 264209, Shandong Province, China
³ School of Chemistry and Chemical Engineering, Northwestern Polytechnical University, Xi'an 710072, Shaanxi Province, China

Received:2026-01-25 Revised:2026-02-26 Accepted:2026-03-01 Published:2026-07-03
Contact: Email: wcyadam@126.com (Chunyu Wang)zhongbo@hit.edu.cn (Bo Zhong)xialong@hit.edu.cn (Long Xia)

摘要/Abstract

摘要：

异质界面的合理构造是改善材料吸波性能一种有效的方法。本研究采用简便的两步水热法合成花瓣状WS₂/MnFe₂O₄/GNs复合材料(其中GNs为石墨烯)。WS₂均匀包覆在多面体MnFe₂O₄颗粒上附着于GNs表面，形成多层三维异质结构。通过调节MnFe₂O₄/GNs的负载量，可有效调控三元复合材料的电磁波吸收特性。当负载量为20%时，RL_min达−44.50 dB，最大有效吸收带宽达4.08 GHz。这归功于花状WS₂、多面体MnFe₂O₄与GNs共同构成的多级微结构，多层结构的存在使得电磁波的反射路径更加丰富，通过多次反射增强能量耗散，另一方面，它改善了材料的阻抗匹配，并强化了磁损耗与介质损耗的协同效应。

关键词: WS₂, 三维网状传导, 微波吸收, MnFe₂O₄/GNs

Abstract:

Rational construction of heterointerfaces represents an effective strategy for exploring high-performance electromagnetic wave absorption. This study employs a simple two-step hydrothermal method to synthesize petal-clustered WS₂/MnFe₂O₄/GNs (where GNs denotes graphene) hybrid materials. WS₂ uniformly coats the polyhedral MnFe₂O₄ particles attached to the GNs surface, forming a multi-layer three-dimensional hetero-structure. By adjusting the MnFe₂O₄/GNs loading, the electromagnetic wave absorption properties of the ternary hybrid material can be effectively tuned. At a MnFe₂O₄/GNs loading of 20%, the minimum reflection loss reaches −44.50 dB, with a maximum effective absorption bandwidth of 4.08 GHz. This is attributed to the multilevel microstructure formed by flower-like WS₂, polyhedral MnFe₂O₄, and GNs.

Key words: WS₂, 3D mesh conduction, Microwave absorption, MnFe₂O₄/GNs

朱耿素, 马媛媛, 孙承志, 李梦婷, 王春雨, 钟博, 夏龙. 花瓣状WS₂/MnFe₂O₄/GNs复合材料展现出高效电磁波吸收性能[J]. 物理化学学报, 2026, 42(9), 100273. doi: 10.1016/j.actphy.2026.100273

Gengsu Zhu, Yuanyuan Ma, Chengzhi Sun, Mengting Li, Chunyu Wang, Bo Zhong, Long Xia. Preparation and absorption properties of petal-clustered WS₂/MnFe₂/O₄/GNs composite materials[J]. Acta Phys. -Chim. Sin. 2026, 42(9), 100273. doi: 10.1016/j.actphy.2026.100273

链接本文: https://www.whxb.pku.edu.cn/CN/10.1016/j.actphy.2026.100273

https://www.whxb.pku.edu.cn/CN/Y2026/V42/I9/100273

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花瓣状WS₂/MnFe₂O₄/GNs复合材料展现出高效电磁波吸收性能

Preparation and absorption properties of petal-clustered WS₂/MnFe₂/O₄/GNs composite materials

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