物理化学学报 >> 1999, Vol. 15 >> Issue (07): 652-656.doi: 10.3866/PKU.WHXB19990714

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Cu/SiO2表面性质对甲醇脱氢反应性能的影响

张荣, 孙予罕, 彭少逸   

  1. 中国科学院山西煤炭化学研究所，煤转化国家重点实验室，太原 030001
  • 收稿日期:1998-08-31 修回日期:1998-12-21 发布日期:1999-07-15
  • 通讯作者:

Effect of Surface Properties on the Catalytic Performance of Cu/SiO2 Catalysts

Zhang Rong, Sun Yu-Han, Peng Shao-Yi   

  1. State Key Laboratory of Coal Conversion,Institute of Coal Chemistry,Chinese Academy of Sciences,Taiyuan 030001
  • Received:1998-08-31 Revised:1998-12-21 Published:1999-07-15
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关键词: 甲醇, 脱氢, Cu/SiO2催化剂, 催化性能

Abstract:

Methanol dehydrogenation over CU/SiO2 prepared by different method was investigated in a fixed-bed reactor TPR was used to characterize the reduction property of the catalysts. Experimental results showed that catalysts with different initial structure exhibited different catalytic behavior in methanol dshydrogenation. With the reaction going on the activity and selecivity of methyl formate and CO decreased and the selectivity of formaldehyde increased due to the sintering and carbon deposition on the surface.

Key words: Cu/SiO2 catalysts, Methanol, Dehydrogenation, Catalytic properties