石英晶体微天平研究Zn在薄液膜下的腐蚀动力学

doi:10.3866/PKU.WHXB20010408

Acta Phys. -Chim. Sin. ›› 2001, Vol. 17 ›› Issue (04): 319-323.doi: 10.3866/PKU.WHXB20010408

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Corrosion Kinetics of Zinc under Thin Electrolyte Film by Means of QCM

Wang Feng-Ping;Yan Chuan-Wei;Zhang Xue-Yuan;Yan Yi-Gong;Du Yuan-Long

State Key Laboratory for Corrosion and Protection,Institute of Metal Research,Chinese Academy of Sciences,Shenyang　110016;2Material Science and Engineering College,Beijing University of Science and Technology,Beijing　100083

Received:2000-07-27 Revised:2000-12-04 Published:2001-04-15
Contact: Wang Feng-Ping E-mail:wang-fp@hotvoice.com

Abstract

Abstract: The corrosion gain weight of electroplated zinc in atmosphere containing different concentrations of CO2 under thin electrolyte film were measured by means of quartz crystal microbalance.Equations of corrosion gain weight were derived from the experiments under the same condition.Atmospheric corrosion mechanism of zinc under thin electrolyte film was also discussed by the equation of corrosion gain weight,combined with Infrared absorption spectroscopy and Xray energy dispersion spectroscopy.Protective features was elucidated by analysis of the morphology of atmospheric corrosion layer on zinc using SEM.

Key words: Quartz crystal microbalance(QCM), Atmospheric corrosion, Corrosion gain weight, Zinc, Thin electrolyte film

Wang Feng-Ping;Yan Chuan-Wei;Zhang Xue-Yuan;Yan Yi-Gong;Du Yuan-Long. Corrosion Kinetics of Zinc under Thin Electrolyte Film by Means of QCM[J]. Acta Phys. -Chim. Sin. 2001, 17(04), 319-323. doi: 10.3866/PKU.WHXB20010408

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Corrosion Kinetics of Zinc under Thin Electrolyte Film by Means of QCM

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