电化学合成Cu3(BTC)2-MOF及用于NH3选择性催化还原NO

doi:10.3866/PKU.WHXB201510141

Abstract

Abstract:

A Cu₃(BTC)₂ (copper(Ⅱ) benzene 1, 3, 5-tricarboxylate) metal organic framework (MOF) catalyst was successfully prepared through an electrochemical route and used for selective catalytic reduction of nitrogen oxide (NO_x) with NH₃ for the first time. After systematically optimizing the reaction conditions such as solvents, voltage, electrolyte concentration, and reaction time, pure Cu₃(BTC)₂ with high crystallinity was obtained in 97.2% yield. The physicochemical properties of the catalyst were determined using X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), thermogravimetric analysis (TGA), Raman spectroscopy, in situ Fourier transform infrared (FTIR) spectroscopy, temperature-programmed desorption (TPD), and X-ray photoelectron spectroscopy (XPS). TGA results indicated that the framework was stable up to 310℃. The catalytic activity of Cu₃(BTC)₂ was evaluated using NO conversion as a model reaction. The Cu₃(BTC)₂ activation temperature significantly affected the catalytic activity. The Cu₃(BTC)₂ sample activated at 240℃ had the best catalytic activity and gave NO conversion of 90% at 220-280℃. A reaction mechanism was proposed based on the in situ FTIR spectroscopy results.

Key words: Electrochemical synthesis, Cu₃(BTC)₂, Metal-organic framework, NO, NH₃-selective catalytic reduction

Zhen-Zhen. LIU,Yong. SHI,Chun-Yan. LI,Qi-Dong. ZHAO,Xin-Yong. LI. Electrochemical Synthesis of Cu₃(BTC)₂-MOF for Selective Catalytic Reduction of NO with NH₃[J]. Acta Phys. -Chim. Sin. 2015, 31(12), 2366-2374. doi: 10.3866/PKU.WHXB201510141

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Electrochemical Synthesis of Cu₃(BTC)₂-MOF for Selective Catalytic Reduction of NO with NH₃

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Electrochemical Synthesis of Cu₃(BTC)₂-MOF for Selective Catalytic Reduction of NO with NH₃