氟离子浓度对稀土掺杂上转换发光纳米材料形貌及荧光寿命的影响

doi:10.3866/PKU.WHXB201605091

Abstract

Abstract:

Up-conversion luminescent NaYF₄:Yb³⁺/Er³⁺ nanomaterials were synthesized using a solvo-thermal method. It was determined that the size, morphology, and luminescence intensity of these nanoparticles can be controlled by varying the concentration of fluoride ions. Low reactant concentrations were found to always result in monodisperse, hexagonal nanocrystals, and to gradually and uniformly decrease the size of the NaYF₄ nanocrystals. In contrast, at higher concentrations, the nanocrystals grow to form a mixed phase. Fluoride ion concentrations over a specific range tend to promote the fluorescence emission of the material and may also significantly affect the fluorescent lifetime.

Key words: Up-conversion luminescent, Nanomaterial, NaYF₄, Morphology control, Fluorescent llifetime

Shan-Shan LIU,Zheng XU,Su-Ling ZHAO,Zhi-Qin LIANG,Wei ZHU. Effects of F^- Concentration on the Morphologies and Fluorescent Lifetimes of Ln³⁺-Doped Up-Conversion Nanocrystals[J]. Acta Phys. -Chim. Sin. 2016, 32(8), 2108-2112. doi: 10.3866/PKU.WHXB201605091

References

1	Wang F. ; Han Y. ; Lim C. S. ; Lu Y. ; Wang J. ; Xu J. ; Chen H. ; Zhang C. ; Hong M. ; Liu X Nature 2010, 463, 1061.
2	Cui Y. ; Zhao S. ; Liang Z. ; Han M. ; Xu Z. J Alloy. Compd 2014, 593, 30.
3	Zhang P. ; Rogelj S. ; Nguyen K. ; Wheeler D. J Am. Chem. Soc 2006, 128, 12410.
4	Haase M. ; Sch?fer H Angew. Chem. Int. Edit 2011, 50, 5808.
5	Xiong L. Q. ; Chen Z. G. ; Yu M. X. ; Li F. Y. ; Liu C. ; Huang C. H Biomaterials 2009, 30, 5592.
6	Cao T. ; Yang T. ; Gao Y. ; Yang Y. ; Hu H. ; Li F Inorg. Chem. Commun 2010, 13, 392.
7	Xie P. ; Gosnell T Opt. Lett 1995, 20, 1014.
8	Downing E. ; Hesselink L. ; Ralston J. ; MacFarlane R Science 1996, 273, 1185.
9	Gao L. N. ; Lü F. T. ; Hu J. ; Fang Y Acta Phys. -Chim. Sin 2007, 23, 274.
9	高莉宁; 吕凤婷; 胡静; 房喻. 物理化学学报, 2007, 23, 274.
10	Liu M. ; Lu Y. ; Xie Z. ; Chow G Sol. Energy Mate. Sol. Cells 2011, 95, 800.
11	Boyer J. C. ; Vetrone F. ; Cuccia L. A. ; Capobianco J. A. J. Am. Chem. Soc 2006, 128, 7444.
12	Kr?mer K.W. ; Biner D. ; Frei G. ; Güdel H. U. ; Hehlen M. P. ; Lüthi S. R Chem. Mater 2004, 16, 1244.
13	Mai H. X. ; Zhang Y.W. ; Sun L. D. ; Yan C. H. J. Phys. Chem. C 2007, 111, 13730.
14	Ma D. ; Yang D. ; Jiang J. ; Cai P. ; Huang S CrystEngComm 2010, 12, 1650.
15	Wang L. ; Li Y Chem. Mater 2007, 19, 727.
16	Yi G. ; Lu H. ; Zhao S. ; Ge Y. ; Yang W. ; Chen D. ; Guo L. H Nano Lett 2004, 4, 2191.
17	Patra A. ; Friend C. S. ; Kapoor R. ; Prasad P. N. J. Phys. Chem. B 2002, 106, 1909.
18	Patra A. ; Friend C. S. ; Kapoor R. ; Prasad P. N Chem. Mater 2003, 15, 3650.
19	Pang Y. C. ; Gan L. H. ; Hao Z. X. ; Xu Z. J. ; Chen L W. Acta Phys. -Chim. Sin 2005, 21 (12), 1363.
19	庞颖聪; 甘礼华; 郝志显; 徐子颉; 陈龙武. 物理化学学报, 2005, 21 (12), 1363.
20	Li Z. ; Zhang Y Nanotechnology 2008, 19, 345606.
21	Li Z. ; Zhang Y. ; Jiang S Adv. Mater 2008, 20, 4765.
22	Zeng J. H. ; Su J. ; Li Z. H. ; Yan R. X. ; Li Y. D Adv. Mater 2005, 17, 2119.
23	Wang X. ; Zhuang J. ; Peng Q. ; Li Y Inorg. Chem 2006, 45, 6661.
24	Cui Y. ; Zhao S. ; Han M. ; Li P. ; Zhang L. ; Xu Z. J. Nanosci. Nanotechnol 2014, 14, 3597.

[1]	Xiaoyu Wang, Yang Cheng, Guodong Xue, Ziqi Zhou, Mengze Zhao, Chaojie Ma, Jin Xie, Guangjie Yao, Hao Hong, Xu Zhou, Kaihui Liu, Zhongfan Liu. Giant Enhancement of Optical Second Harmonic Generation in Hollow-Core Fiber Integrated with GaSe Nanoflakes [J]. Acta Phys. -Chim. Sin., 2023, 39(7): 2212028-0.
[2]	Jie Wang, Guigao Liu, Qinbai Yun, Xichen Zhou, Xiaozhi Liu, Ye Chen, Hongfei Cheng, Yiyao Ge, Jingtao Huang, Zhaoning Hu, Bo Chen, Zhanxi Fan, Lin Gu, Hua Zhang. Epitaxial Growth of Unconventional 4H-Pd Based Alloy Nanostructures on 4H-Au Nanoribbons towards Highly Efficient Electrocatalytic Methanol Oxidation [J]. Acta Phys. -Chim. Sin., 2023, 39(10): 2305034-.
[3]	Changxiang Shao, Liangti Qu. Progress on Power Generation from Gas-Liquid Phase Transformation of Water [J]. Acta Phys. -Chim. Sin., 2023, 39(10): 2306004-.
[4]	Wenqian He, Ya Di, Nan Jiang, Zunfeng Liu, Yongsheng Chen. Graphene-Oxide Seeds Nucleate Strong and Tough Hydrogel-Based Artificial Spider Silk [J]. Acta Phys. -Chim. Sin., 2022, 38(9): 2204059-.
[5]	Cheng Chang, Wei Chen, Ye Chen, Yonghua Chen, Yu Chen, Feng Ding, Chunhai Fan, Hong Jin Fan, Zhanxi Fan, Cheng Gong, Yongji Gong, Qiyuan He, Xun Hong, Sheng Hu, Weida Hu, Wei Huang, Yuan Huang, Wei Ji, Dehui Li, Lain-Jong Li, Qiang Li, Li Lin, Chongyi Ling, Minghua Liu, Nan Liu, Zhuang Liu, Kian Ping Loh, Jianmin Ma, Feng Miao, Hailin Peng, Mingfei Shao, Li Song, Shao Su, Shuo Sun, Chaoliang Tan, Zhiyong Tang, Dingsheng Wang, Huan Wang, Jinlan Wang, Xin Wang, Xinran Wang, Andrew T. S. Wee, Zhongming Wei, Yuen Wu, Zhong-Shuai Wu, Jie Xiong, Qihua Xiong, Weigao Xu, Peng Yin, Haibo Zeng, Zhiyuan Zeng, Tianyou Zhai, Han Zhang, Hui Zhang, Qichun Zhang, Tierui Zhang, Xiang Zhang, Li-Dong Zhao, Meiting Zhao, Weijie Zhao, Yunxuan Zhao, Kai-Ge Zhou, Xing Zhou, Yu Zhou, Hongwei Zhu, Hua Zhang, Zhongfan Liu. Recent Progress on Two-Dimensional Materials [J]. Acta Phys. -Chim. Sin., 2021, 37(12): 2108017-.
[6]	Ning Feng, Hongguang Li, Jingcheng Hao. Toward the Neutralization of Carbon Dots Prepared by Mixed Acid Reflux [J]. Acta Phys. -Chim. Sin., 2021, 37(10): 2005004-.
[7]	Jing Zhang, Lina Wang, Xiaofei Chen, Yufeng Wang, Chengyan Niu, Lixin Wu, Zhiyong Tang. Redox-Regulated Dynamic Self-Assembly of a Lindqvist-Type Polyoxometalate Complex [J]. Acta Physico-Chimica Sinica, 2020, 36(9): 1912002-.
[8]	Yuan Zhou, Na Han, Yanguang Li. Recent Progress on Pd-based Nanomaterials for Electrochemical CO₂ Reduction [J]. Acta Physico-Chimica Sinica, 2020, 36(9): 2001041-.
[9]	Chao Zhang, Sihan Li, Chenliang Wu, Xiaoqing Li, Xinhuan Yan. Preparation and Characterization of Pt@Au/Al₂O₃ Core-Shell Nanoparticles for Toluene Oxidation Reaction [J]. Acta Physico-Chimica Sinica, 2020, 36(8): 1907057-.
[10]	Dongmei Liu,Xiumei Chen,Ze Yuan,Min Lu,Lisha Yin,Xiaoji Xie,Ling Huang. Coating and Transforming the Y(OH)CO₃ Shell on Upconversion Nanoparticles [J]. Acta Physico-Chimica Sinica, 2020, 36(7): 1907011-.
[11]	Jing Miao,Ruifeng Guo,Zhihong Liu. Preparation of BaO·4B₂O₃·5H₂O Nanomaterial and Evaluation of Its Flame Retardant Performance to PP by Thermal Decomposition Kinetics Method [J]. Acta Physico-Chimica Sinica, 2020, 36(6): 1905052-.
[12]	Ruolan Zhang,Chao Wang,Hao Chen,Heng Zhao,Jing Liu,Yu Li,Baolian Su. Cadmium Sulfide Inverse Opal for Photocatalytic Hydrogen Production [J]. Acta Physico-Chimica Sinica, 2020, 36(3): 1803014-.
[13]	Yi Wang,Wangchen Huo,Xiaoya Yuan,Yuxin Zhang. Composite of Manganese Dioxide and Two-dimensional Materials Applied to Supercapacitors [J]. Acta Physico-Chimica Sinica, 2020, 36(2): 1904007-.
[14]	Zhanhong Du, Yi Lu, Pengfei Wei, Chunshan Deng, Xiaojian Li. Progress in Devices and Materials for Implantable Multielectrode Arrays [J]. Acta Phys. -Chim. Sin., 2020, 36(12): 2007004-.
[15]	Qingqing WANG, Jinling WANG, Shengxiang JIANG, Pingyun LI. Recent Progress in Sol-Gel Method for Designing and Preparing Metallic and Alloy Nanocrystals [J]. Acta Physico-Chimica Sinica, 2019, 35(11): 1186-1206.

Effects of F^- Concentration on the Morphologies and Fluorescent Lifetimes of Ln³⁺-Doped Up-Conversion Nanocrystals

RichHTML

PDF

Like

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Metrics

Recommended 0

Effects of F- Concentration on the Morphologies and Fluorescent Lifetimes of Ln3+-Doped Up-Conversion Nanocrystals

RichHTML

PDF

Like

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Metrics

Recommended 0

Effects of F^- Concentration on the Morphologies and Fluorescent Lifetimes of Ln³⁺-Doped Up-Conversion Nanocrystals