金属螯合物印迹聚邻苯二胺膜的电化学合成及表征

doi:10.3866/PKU.WHXB20110628

Acta Phys. -Chim. Sin. ›› 2011, Vol. 27 ›› Issue (06): 1451-1456.doi: 10.3866/PKU.WHXB20110628

• ELECTROCHEMISTRY AND NEW ENERGY • Previous Articles Next Articles

Electrosynthesis and Characterization of Metal Chelate Imprinted Poly-o-Phenylenediamine Films

WANG Lian-Yan¹, LU Feng², WU Fu-Quan³, GU Ren-Ao², YAO Jian-Lin², ZHANG Hai-Lu¹, DENG Zong-Wu¹

1. Suzhou Institute of Nano-tech and Nano-bionics, Chinese Academy of Sciences, Suzhou 215123, Jiangsu Province, P. R. China;
2. College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, Jiangsu Province, P. R. China;
3. Suzhou Environmental Monitor Centre, Suzhou 215004, Jiangsu Province, P. R. China

Received:2011-01-14 Revised:2011-04-12 Published:2011-05-31
Contact: DENG Zong-Wu E-mail:zwdeng2007@sinano.ac.cn
Supported by:
The project was supported by the National Natural Science Foundation of China (21073226) and Science and Technology Planning Project of Suzhou, China (SS0852).

Abstract

Abstract:

Novel molecularly imprinted polymers (MIPs) were synthesized by the electrochemical polymerization of o-phenylenediamine (o-PD) using cyclic voltammetry in the presence of Cu(II)- ethylenediaminetetraacetate chelate (Cu(II)-EDTA), which acted as a template. The resultant polymers were characterized by UV-Vis spectroscopy, X-ray photoelectron spectroscopy (XPS), differential pulse voltammetry (DPV), and quartz crystal microbalance (QCM). UV-Vis spectral analysis indicated that a higher degree poly-o-phenylenediamine (PoPD) was obtained at pH≥5.0. XPS analysis clearly showed the successful embedding of a Cu(II)-EDTA chelate in the PoPD film and, therefore, hydrogen bonding was a major interaction between the template and the PoPD film. DPV analysis confirmed the successful removal of the template from the PoPD film. The QCM test showed that the Cu(II)-EDTA imprinted PoPD film had good Cu(II)-EDTA chelate sensitivity.

Key words: o-Phenylenediamine, Chelate, Molecularly imprinted polymer, Cyclic voltammetry, Quartz crystal microbalance

WANG Lian-Yan, LU Feng, WU Fu-Quan, GU Ren-Ao, YAO Jian-Lin, ZHANG Hai-Lu, DENG Zong-Wu. Electrosynthesis and Characterization of Metal Chelate Imprinted Poly-o-Phenylenediamine Films[J]. Acta Phys. -Chim. Sin. 2011, 27(06), 1451-1456. doi: 10.3866/PKU.WHXB20110628

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Electrosynthesis and Characterization of Metal Chelate Imprinted Poly-o-Phenylenediamine Films

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