对苯二甲酸镁作为钠离子电池的有机负极材料

doi:10.3866/PKU.WHXB201408052

Abstract

Abstract:

In this study, the electrochemical properties of magnesium terephthalate with hydration water (MgC₈H₄O₄·2H₂O) as an anode material for sodium ion batteries were investigated for the first time. MgC₈H₄O₄· 2H₂O was synthesized via a facile neutralization method using terephthalic acid (C₈H₆O₄) and magnesium hydroxide (Mg(OH)₂) as precursors. Good cycle performance was obtained as 114 mAh·g^-1 was found for the second cycle and 95 mAh·g^-1 was obtained after 50 cycles at a current rate of 0.5C (1C=300 mA·g^-1), giving a capacity retention of 84%. At a current rate of 2C, it presents a discharge capacity of 90 mAh·g^-1. After heating under a nitrogen atmosphere at 400 ℃, anhydrous magnesium terephthalate (MgC₈H₄O₄) was obtained. The effect of hydration water on the crystal structure, morphology, and electrochemical properties was investigated. The results indicate that the specific discharge capacity, rate capacity, and cyclic performance of MgC₈H₄O₄· 2H₂O are better than those of MgC₈H₄O₄.

Key words: Magnesium terephthalate, Organic electrode material, Sodium ion battery, Hydration water, Neutralization reaction

HUANG Zong-Ling, WANG Li-Ping, MOU Cheng-Xu, LI Jing-Ze. Magnesium Terephthalate as an Organic Anode Material for Sodium Ion Batteries[J]. Acta Phys. -Chim. Sin. 2014, 30(10), 1787-1793. doi: 10.3866/PKU.WHXB201408052

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Magnesium Terephthalate as an Organic Anode Material for Sodium Ion Batteries

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