锂离子电池高比容量FeSn2-C复合负极材料的合成与性能

doi:10.3866/PKU.WHXB201405071

Acta Phys. -Chim. Sin. ›› 2014, Vol. 30 ›› Issue (7): 1281-1289.doi: 10.3866/PKU.WHXB201405071

• ELECTROCHEMISTRY AND NEW ENERGY • Previous Articles Next Articles

Synthesis and Properties of FeSn₂-C Composites as Anode Materials for Lithium-Ion Batteries

LIU Xin¹, XIE Jing-Ying², ZHAO Hai-Lei^1,3, LÜ Peng-Peng¹, WANG Ke², FENG Zhen-He², WANG Meng-Wei²

1. School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083, P. R. China;
2. Shanghai Institute of Space Power Sources, Shanghai 200245, P. R. China;
3. Beijing Key Laboratory of New Energy Materials and Technology, Beijing 100083, P. R. China

Received:2014-02-10 Revised:2014-05-07 Published:2014-06-30
Contact: XIE Jing-Ying, ZHAO Hai-Lei E-mail:xiejingying2007@126.com;hlzhao@ustb.edu.cn
Supported by:
The project was supported by the National Natural Science Foundation of China (21273019), National Key Basic Research Program of China (973) (2013CB934003), National High Technology Research and Development Program of China (863) (2013AA050902), Shanghai Science and Technology Talent Project Funds, Chian (12XD1421900), and Shanghai Science and Technology Development Funds, China (12dz1200503, 13dz2280200).

Abstract

Abstract:

Tin has a theoretical specific capacity as high as 990 mAh·g^-1, and is thus a potential anode material for high-energy-density lithium-ion batteries. However, it suffers from a huge volume change during lithiation/delithiation process, leading to poor cycle performance. In this paper, core/shell structured FeSn₂-C composites were successfully synthesized by a simple high-energy ball milling technique with Sn, Fe, and graphite powder as raw materials. The FeSn₂-C composite was evaluated as an anode material for lithium-ion batteries. The influence of milling time and final phase composition on the microstructure and electrochemical performance of FeSn₂-C composites was systematically investigated. The failure mechanism of the FeSn₂-C electrode was also analyzed. The results reveal that long milling time can promote the mechanical alloying process of the FeSn₂ phase and reduce the particle size of the FeSn₂-C composite, which are beneficial for the increase of the specific capacity and the improvement of the cycle performance of the FeSn₂-C electrode. A high FeSn₂ phase content leads to a high specific capacity of the FeSn₂-C composites but poor cycling stability of the electrode. The optimized Sn₂₀Fe₁₀C₇₀ composite prepared by ball milling for 24 h (500 r ·min^-1) shows the best electrochemical performance with a capacity about 540 mAh·g^-1 for 100 cycles. The synthesized Sn₂₀Fe₁₀C₇₀ composite is a promising anode material for highenergy-density lithium-ion batteries.

Key words: FeSn₂-C composite, Phase composition, High-energy ball milling, Anode material, Lithium-ion battery

LIU Xin, XIE Jing-Ying, ZHAO Hai-Lei, Lü Peng-Peng, WANG Ke, FENG Zhen-He, WANG Meng-Wei. Synthesis and Properties of FeSn₂-C Composites as Anode Materials for Lithium-Ion Batteries[J]. Acta Phys. -Chim. Sin. 2014, 30(7), 1281-1289. doi: 10.3866/PKU.WHXB201405071

References

(1) Zhamu, A.; Chen, G.; Liu, C.; Neff, D.; Fang Q.; Yu, Z.; Xiong, W.;Wang, Y.;Wang, X.; Jang, B. Z. Energy & Environ. Sci. 2012, 5, 5701.
(2) Chang, Y. Q.; Huang, L.; Sun, S. G. Acta Phys. -Chim. Sin. 2010, 26, 561. [常玉清, 黄令, 孙世刚. 物理化学学报, 2010, 26, 561.]
(3) Guo, H.; Zhao, H.; Jia, X.; Li, X.; Qiu,W. Electrochim. Acta 2007, 52, 4853.
(4) Liang, C.; Gao, M.; Pan, H.; Liu, Y.; Yan, M. J. Alloy. compd. 2013, 575, 246.
(5) Liu, X.; Xie, J. Y.; Zhao, H. L.;Wang, K.; Tang,W. P.; Pan, Y. L.; Feng, Z. H.; LÜ, P. P. Acta Chim. Sin. 2013, 71, 1011. [刘欣, 解晶莹, 赵海雷, 王可, 汤卫平, 潘延林, 丰震河, 吕鹏鹏. 化学学报, 2013, 71, 1011]
(6) Zhang,W. J. J. Power Sources 2011, 196, 13.
(7) Todd, A. D.W.; Mar, R. E.; Dahn, J. R. J. Electrochem. Soc. 2006, 153, A1998.
(8) Guo, H.; Zhao, H.; Jia, X. Electrochem. Commun. 2007, 9, 2207.
(9) Fan, X. Y.; Zhuang, Q. C.;Wei, G. Z.; Ke, F. S.; Huang, L.; Dong, Q. F.; Sun, S. G. Acta Phys. -Chim. Sin. 2009, 25, 611. [樊小勇, 庄全超, 魏国祯, 柯福生, 黄令, 董全峰, 孙世刚. 物理化学学报, 2009, 25, 611.]
(10) Zhang,W. J. J. Power Sources 2011, 196, 877.
(11) Ferguson, P. P.; Todd, A. D.W.; Dahn, J. R. Electrochem. Commun. 2008, 10, 25.
(12) Jung, H. R.;Wan, J. L. J. Electrochem. Soc. 2011, 158, A644.
(13) Mao, O.; Dunlap, R. A.; Dahn, J. R. J. Electrochem. Soc. 1999, 146, 405.
(14) Mao, O.; Dahn, J. R. J. Electrochem. Soc. 1999, 146, 414.
(15) Mao, O.; Dahn, J. R. J. Electrochem. Soc. 1999, 146, 423.
(16) Yoon, S.; Lee, J. M.; Kim, H.; Im, D.; Doo, S. G.; Sohn, H. J. Electrochim. Acta 2009, 54, 2699.
(17) Lee, J. M.; Jung, H.; Hwa, Y.; Kim, H.; Im, D.; Doo, S. G.; Sohn, H.J. J. Power Sources 2010, 195, 5044.
(18) Ferguson, P. P.; Liao, P.; Dunlap, R. A.; Dahn, J. R. J. Electrochem. Soc. 2009, 156, A13.
(19) Holzwarth, U.; Gibson, N. Nat. Nanotechnol. 2011, 6, 534.
(20) Todd, A. D.W.; Ferguson, P. P.; Fleischauer, M. D.; Dahn, J. R. Int. J. Energy Res. 2010, 34, 535.
(21) Chamas, M.; Lippens, P. E.; Jumas, J. C.; Boukerma, K.; Dderyvere, R.; Gonbeau, D.; Hassoun, J.; Panero, S.; Scrosati, B. J. Power Sources 2011, 196, 7011.
(22) Zhang, C. Q.; Tu, J. P.; Huang, X. H.; Yuan, Y. F.;Wang, S. F.; Mao, F. J. Alloy. Compd. 2008, 457, 81.

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Synthesis and Properties of FeSn₂-C Composites as Anode Materials for Lithium-Ion Batteries

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