氮、硫共掺杂的碳负载的钴@碳化钴:一种高效的非贵金属氧还原电催化剂

doi:10.3866/PKU.WHXB201704264

Abstract

Abstract:

Development of high-efficiency and low-cost electrocatalysts for large-scale oxygen reduction reaction (ORR) remains a challenge. In this study, we employed melamine, trithiocyanuric acid, and cobaltous nitrate to fabricate a novel ORR electrocatalyst with cobalt and cobalt carbide supported on carbon co-doped with nitrogen and sulfur (hereafter referred to as MTC-0.1-900) by two-step pyrolysis. The MTC-0.1-900 was characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), Raman spectroscopy, Brunauer-Emmett-Teller (BET) specific surface area analysis, and X-ray photoelectron spectroscopy (XPS). The electrochemical performance for ORR was investigated by cyclic voltammetry and linear sweep voltammetry in 0.1 mol·L^-1 KOH solutions. The results showed that the onset potential and half-wave potential of MTC-0.1-900 were 29 and 5 mV superior to the commercial Pt/C catalyst, respectively. After 12000 s operation at the potential of -0.3 V (vs Ag/AgCl), the current retention capacities of MTC-0.1-900 and Pt/C were 97.1% and 76.7%, respectively. MTC-0.1-900 also showed better methanol tolerance than Pt/C. These unique properties of MTC-0.1-900 provide us with an alternative for replacing or reducing the use of Pt catalyst in metal-air battery cathode materials.

Key words: Nitrogen and sulfur co-doped carbon, Cobalt@cobalt carbide, Graphitic carbon, Core-shell, Oxygen reduction reaction

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Hai-Bo SHEN,Hao JIANG,Yi-Si LIU,Jia-Yu HAO,Wen-Zhang LI,Jie LI. Cobalt@cobalt Carbide Supported on Nitrogen and Sulfur Co-Doped Carbon: an Efficient Non-Precious Metal Electrocatalyst for Oxygen Reduction Reaction[J]. Acta Phys. -Chim. Sin. 2017, 33(9), 1811-1821. doi: 10.3866/PKU.WHXB201704264

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Cobalt@cobalt Carbide Supported on Nitrogen and Sulfur Co-Doped Carbon: an Efficient Non-Precious Metal Electrocatalyst for Oxygen Reduction Reaction

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