硫化镉反蛋白石光子晶体制备及光解水制氢

doi:10.3866/PKU.WHXB201803014

物理化学学报 >> 2020, Vol. 36 >> Issue (3): 1803014.doi: 10.3866/PKU.WHXB201803014

所属专题：光催化剂

硫化镉反蛋白石光子晶体制备及光解水制氢

张若兰¹,王超¹,陈浩¹,赵恒¹,刘婧¹,李昱^1,^2,*(),苏宝连^1,³

¹ 武汉理工大学材料复合新技术国家重点实验室，武汉 430070
² 武汉理工大学纳微结构研究中心，武汉 430070
³ 那慕尔大学无机材料化学实验室，布鲁塞尔街61号，比利时那慕尔 B-5000

收稿日期:2019-03-05 录用日期:2019-04-09 发布日期:2019-04-12
通讯作者: 李昱 E-mail:yu.li@whut.edu.cn
基金资助:
国家重点研发计划(2016YFA0202602);国家自然科学基金(U1663225);国家自然科学基金(21671155);国家自然科学基金(21805220);湖北省自然科学基金(2018CFB242);湖北省自然科学基金(2018CFA054);湖北省技术创新专项重大项目(2018AAA012);教育部长江创新团队(IRT_15R52)

Cadmium Sulfide Inverse Opal for Photocatalytic Hydrogen Production

Ruolan Zhang¹,Chao Wang¹,Hao Chen¹,Heng Zhao¹,Jing Liu¹,Yu Li^1,^2,*(),Baolian Su^1,³

¹ State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, P. R. China
² Nanostructure Research Centre (NRC), Wuhan University of Technology, Wuhan 430070, P. R. China
³ Laboratory of Inorganic Materials Chemistry (CMI), University of Namur, 61 rue de Bruxelles, B-5000 Namur, Belgium

Received:2019-03-05 Accepted:2019-04-09 Published:2019-04-12
Contact: Yu Li E-mail:yu.li@whut.edu.cn
Supported by:
National Key R & D Program of China(2016YFA0202602);National Natural Science Foundation of China(U1663225);National Natural Science Foundation of China(21671155);National Natural Science Foundation of China(21805220);Natural Science Foundation of Hubei Province, China(2018CFB242);Natural Science Foundation of Hubei Province, China(2018CFA054);Major Programs of Technical Innovation in Hubei, China(2018AAA012);Program for Changjiang Scholars Innovative Research Team in University, China(IRT_15R52)

摘要/Abstract

摘要：

对硫化镉反蛋白石结构光子晶体薄膜进行了可控合成，用巯基乙酸修饰的纳米晶和P(St-MMA-SPMAP)高分子小球共组装，成功地构筑了反蛋白石结构并用于可见光光解水产氢。结果表明，在可见光(λ ≥ 420 nm)照射下，CdS-310反蛋白石结构薄膜的光解水产氢性能比硫化镉纳米颗粒提高了一倍。这主要是因为等级孔结构反蛋白石光子晶体特性对催化剂的光催化性能的提升：首先，反蛋白石的周期性结构增加了光子在材料中的传播，提高了催化剂对太阳光的利用率；同时，大孔孔壁是由纳米颗粒堆积而成的，在反应中提供了更多的反应活性位点；此外，孔结构有利于物质的传输和分子的吸附。

关键词: 硫化镉, 光子晶体, 反蛋白石结构, 纳米材料, 光解水产氢

Abstract:

Photocatalysis based on visible light is an efficient and promising strategy to convert solar energy into chemical energy and solve the global issues of environmental pollution and energy shortages. CdS, as a visible light responsive semiconductor material, is widely used in photocatalysis and photoluminescence because of its simple synthesis, abundant raw materials, and appropriate bandgap structure. The inverse opal (IO) structure belonging to photonic crystal structure with unique three-dimensionally ordered macro-mesopore, which can tune the propagation direction of incident light and improve photocatalytic performance. Therefore, IO has attracted extensive attention for photocatalysis applications. Herein, CdS IO photonic crystal films were prepared by co-assembly using CdS nanocrystals and poly(styrene-methyl methacrylate-3-sulfopropyl methacrylate, potassium salt) (P(St-MMA-SPMAP)) emulsion. This method is widely used because it is simple and can rapidly prepare large photonic crystal films. The pore size of the IO structure was regulated by changing the diameter of the polymer. The IO structure was characterized using scanning electron microscopy (SEM), X-ray diffraction (XRD), ultraviolet-visible absorption spectroscopy (UV-Vis), and reflectance spectroscopy. The photocatalysis performance of three samples was evaluated via photocatalytic water splitting under visible light irradiation (λ ≥ 420 nm). The photocatalytic hydrogen production rate of the CdS IO film fabricated using a 310 nm P(St-MMA-SPMAP) template (CdS-310) was twice that of CdS nanoparticles (CdS-NPs) under visible light irradiation. This photocatalytic performance enhancement was ascribed to the hierarchically porous structure of the IO photonic crystal. On the one hand, the IO structure increased the propagation of photons in the photocatalytic material and improved sunlight utilization. On the other hand, the structure is conductive to transport and adsorption of molecules. In addition, the IO structure was composed of nanoparticles, providing more active sites for the photocatalytic reaction.

Key words: CdS, Photonic crystal, Inverse opal, Nanomaterials, Photocatalytic hydrogen production

张若兰,王超,陈浩,赵恒,刘婧,李昱,苏宝连. 硫化镉反蛋白石光子晶体制备及光解水制氢[J]. 物理化学学报, 2020, 36(3), 1803014. doi: 10.3866/PKU.WHXB201803014

Ruolan Zhang,Chao Wang,Hao Chen,Heng Zhao,Jing Liu,Yu Li,Baolian Su. Cadmium Sulfide Inverse Opal for Photocatalytic Hydrogen Production[J]. Acta Physico-Chimica Sinica 2020, 36(3), 1803014. doi: 10.3866/PKU.WHXB201803014

链接本文: https://www.whxb.pku.edu.cn/CN/10.3866/PKU.WHXB201803014

https://www.whxb.pku.edu.cn/CN/Y2020/V36/I3/1803014

图/表 11

图1

图2

图3

图4

图5

图6

图7

图8

图9

表1

图10

参考文献 28

1	Kudo A. ; Miseki Y. Chem. Soc. Rev. 2009, 38, 253. doi: 10.1039/b800489g
2	Cui H. Q. ; Jing L. Q. ; Xie M. Z. ; Li Z. J. Acta Phys.-Chim. Sin. 2014, 30, 1903. doi: 10.3866/PKU.WHXB201407173
	崔海琴; 井立强; 谢明政; 李志君. 物理化学学报, 2014, 30, 1903. doi: 10.3866/PKU.WHXB201407173
3	Bahnemann D. ; Henglein A. ; Lilie J. ; Spanhel L. J. J. Phys. Chem. 1984, 88, 709. doi: 10.1021/j150648a018
4	Tong H. ; Ouyang S. X. ; Bi Y. ; Umezawa N. ; Oshikiri M. ; Ye J. H. Adv. Mater. 2012, 43, 229. doi: 10.1002/adma.201102752
5	Chen X. B. ; Mao S. S. Chem. Rev. 2007, 107, 2891. doi: 10.1021/cr0500535
6	Yang Y. X. ; Guo Y. N. ; Liu F. Y. ; Yuan X. ; Guo Y. H. ; Zhang S. Q. ; Guo W. ; Huo M. X. Appl. Catal. B-Environ. 2013, 142, 828. doi: 10.1016/j.apcatb.2013.06.026
7	Du X. H. ; Li Y. ; Yin H. ; Xiang Q. J. Acta Phys. -Chim. Sin. 2018, 34, 414. doi: 10.3866/PKU.WHXB201708283
	杜新华; 李阳; 殷辉; 向全军. 物理化学学报, 2018, 34, 414. doi: 10.3866/PKU.WHXB201708283
8	Yan H. J. ; Yang J. H. ; Ma G. J. ; Wu G. P. ; Zong X. ; Lei Z. B. ; Shi J. Y. ; Li C. J. Catal. 2009, 266, 165. doi: 10.1016/j.jcat.2009.06.024
9	Liu Z. M. ; Liu G. L. ; Hong X. L. Acta Phys. -Chim. Sin. 2018, 35, 215. doi: 10.3866/PKU.WHXB201803061
	刘志明; 刘国亮; 洪昕林. 物理化学学报, 2018, 35, 215. doi: 10.3866/PKU.WHXB201803061
10	Tongying P. ; Plashnitsa V. V. ; Petchsang N. ; Vietmeyer F. ; Ferraudi G. J. ; Kryloya G. ; Kuno M. J. Phys. Chem. Lett. 2012, 3, 3234. doi: 10.1021/jz301628b
11	Acharya K. P. ; Khnayzer R. S. ; O'Connor T. ; Diederich G. ; Kirsanova M. ; Klinkova A. ; Roth D. ; Kinder E. ; Imboden M. ; Zamkov M. Nano Lett. 2011, 11, 2919. doi: 10.1021/nl201388c
12	Zakhidov A. A. ; Baughman R. H. ; Iqbal Z. ; Cui C. ; Khayrullin I. ; Dantas S. O. ; Marti J. ; Ralchenko V. G. Science 1998, 282, 897. doi: 10.1126/science.282.5390.897
13	John S. Phys. Rev. Lett. 1987, 58, 2486. doi: 10.1103/PhysRevLett.58.2486
14	Braun P. V. ; Wiltzius P. Adv. Mater. 2001, 13, 482. doi: 10.1002/1521-4095(200104)13:7<482::Aid-Adma482>3.0.Co;2-4
15	Raccis R. ; Nikoubashman A. ; Retsch M. ; Jonas U. ; Koynov K. ; Butt H. -J. ; Likos C. N. ; Fytas G. ACS Nano 2011, 5, 4607. doi: 10.1021/nn200767x
16	Meng S. ; Li D. ; Zheng X. ; Wang J. ; Chen J. ; Fang J. ; Shao Y. ; Fu X. J. Mater. Chem. A 2013, 1, 2744. doi: 10.1039/c2ta01327d
17	Zhao H. ; Wu M. ; Liu J. ; Deng Z. ; Li Y. ; Su B. L. Appl. Catal. B-Environ. 2016, 184, 182. doi: 10.1016/j.apcatb.2015.11.018
18	Chen J. I. L. ; Von Freymann G. ; Choi S. Y. ; Kitaev V. ; Ozin G. A. Adv. Mater. 2006, 18, 1915. doi: 10.1002/adma.200600588
19	Wang J. S. ; Wang E. J. ; Yu Y. L. ; Guo L. M. ; Cao Y. A. Acta Phys. -Chim. Sin. 2014, 30, 513. doi: 10.3866/PKU.WHXB201401073
	王景声; 王恩君; 于彦龙; 郭丽梅; 曹亚安. 物理化学学报, 2014, 30, 513. doi: 10.3866/PKU.WHXB201401073
20	Liu J. ; Jin J. ; Li Y. ; Huang H. -W. ; Wang C. ; Wu M. ; Chen L. -H. ; Su B.-L. J. Mater. Chem. A 2014, 2, 5051. doi: 10.1039/c3ta15044e
21	Özbay E. ; Tuttle G. ; Sigalas M. ; Soukoulis C. M. ; Ho K. M. Phys. Rev. B 1995, 51, 13961. doi: 10.1103/PhysRevB.51.13961
22	Xu Y. ; Sun H. B. ; Ye J. Y. ; Matsuo S. ; Misawa H. J. Opt. Soc. Am. B 2001, 18, 1084. doi: 10.1364/JOSAB.18.001084
23	Baba T. ; Kamizawa N. ; Ikeda M. Physica B 1996, 227, 415. doi: 10.1016/0921-4526(96)00457-7
24	Wang M. Q. ; Wang X. G. Sol. Energ. Mat. Sol. C 2008, 92, 357. doi: 10.1016/j.solmat.2007.10.001
25	Yang L. L. ; Yang Z. H. ; Cao W. X. ; Chen L. ; Xu J. ; Zhang H. Z. J. Phys. Chem. B 2005, 109, 11501. doi: 10.1021/jp050242r
	杨凌露; 丛海林; 曹维孝. 高分子学报, 2005, 109, 11501. doi: 10.1021/jp050242r
26	Yang L. -L. ; Cong H. -L. ; Cao W.-X. Acta Polym. Sin. 2005, 1, 223. doi: 10.3321/j.issn:1000-3304.2005.02.013
27	Zhang H. ; Zhou Z. ; Yang B. ; Gao M. Y. J. Phys. Chem. B 2003, 107, 8. doi: 10.1021/jp025910c
28	Sadakane M. ; Sasaki K. ; Nakamura H. ; Yamamoto T. ; Ninomiya W. ; Ueda W. Langmuir 2012, 28, 17766. doi: 10.1021/la303921u

	λ/nm	D/nm	θ/(°)	f/%
CdS-310	562	270	90	24.8
CdS-380	573	315	90	14.3

[1]	王晓愚, 程阳, 薛国栋, 周子琦, 赵孟泽, 马超杰, 谢瑾, 姚光杰, 洪浩, 周旭, 刘开辉, 刘忠范. 基于硒化镓纳米片填充的空芯光纤超高二次谐波增强[J]. 物理化学学报, 2023, 39(7): 2212028 -0 .
[2]	项景超, 李静君, 杨雪, 高水英, 曹荣. 阳离子镍基MOF自组装CdS/PFC-8催化剂用于可见光光催化选择性苯甲醇氧化耦合产氢[J]. 物理化学学报, 2023, 39(4): 2205039 -0 .
[3]	汪婕, 刘贵高, 韵勤柏, 周希琛, 刘效治, 陈也, 程洪飞, 葛一瑶, 黄京韬, 胡兆宁, 陈博, 范战西, 谷林, 张华. 在4H晶相Au纳米带上外延生长非常规晶相4H-Pd基合金纳米结构用于高效甲醇电催化氧化[J]. 物理化学学报, 2023, 39(10): 2305034 - .
[4]	邵长香, 曲良体. 水的气-液相转变获取电能研究进展[J]. 物理化学学报, 2023, 39(10): 2306004 - .
[5]	何文倩, 邸亚, 姜南, 刘遵峰, 陈永胜. 石墨烯诱导水凝胶成核的高强韧人造蛛丝[J]. 物理化学学报, 2022, 38(9): 2204059 - .
[6]	韩高伟, 徐飞燕, 程蓓, 李佑稷, 余家国, 张留洋. 反蛋白石结构ZnO@PDA用于增强光催化产H₂O₂性能[J]. 物理化学学报, 2022, 38(7): 2112037 - .
[7]	尚念泽, 程熠, 敖申, 姑力米热, 李梦文, 王晓愚, 洪浩, 李泽晖, 张晓艳, 符汪洋, 刘开辉, 刘忠范. 基于石墨烯光子晶体光纤的流体传感器[J]. 物理化学学报, 2022, 38(12): 2108041 - .
[8]	冯宁, 李洪光, 郝京诚. 基于混酸回流制备碳点的中和过程[J]. 物理化学学报, 2021, 37(10): 2005004 - .
[9]	王苗, 郑虹宁, 许菲. 异氰酸苯酯诱导的类胶原多肽自组装[J]. 物理化学学报, 2021, 37(10): 1911039 - .
[10]	周远, 韩娜, 李彦光. 钯基纳米材料电化学还原二氧化碳研究进展[J]. 物理化学学报, 2020, 36(9): 2001041 - .
[11]	张超, 李思汉, 吴辰亮, 李小青, 严新焕. Pt@Au/Al₂O₃核壳纳米粒子的制备和表征及其在催化氧化甲苯中的应用[J]. 物理化学学报, 2020, 36(8): 1907057 - .
[12]	刘冬梅,陈秀梅,袁泽,闾敏,殷丽莎,谢小吉,黄岭. 上转换纳米粒子的Y(OH)CO₃壳层包覆及壳层转化[J]. 物理化学学报, 2020, 36(7): 1907011 - .
[13]	苗静,郭睿凤,刘志宏. BaO∙4B₂O₃∙5H₂O纳米材料的制备及其对聚丙烯阻燃性能的热分解动力学方法评价[J]. 物理化学学报, 2020, 36(6): 1905052 - .
[14]	王易,霍旺晨,袁小亚,张育新. 二氧化锰与二维材料复合应用于超级电容器[J]. 物理化学学报, 2020, 36(2): 1904007 - .
[15]	都展宏, 鲁艺, 蔚鹏飞, 邓春山, 李骁健. 植入式神经电极阵列器件与材料的研究进展[J]. 物理化学学报, 2020, 36(12): 2007004 - .

硫化镉反蛋白石光子晶体制备及光解水制氢

Cadmium Sulfide Inverse Opal for Photocatalytic Hydrogen Production

RichHTML

PDF

赞

可视化

摘要/Abstract

引用本文

使用本文

图/表 11

参考文献 28

相关文章 15

Metrics

推荐阅读 0