电解-电化学混合电容器的制备与性能

doi:10.3866/PKU.WHXB201303122

Abstract

Abstract:

To solve the issue of comparatively low operation voltage of electrochemical capacitors, a hybrid capacitor consisting of the anode electrode of tantalum electrolytic capacitor and the cathode electrode of polyaniline (PANI)/TiO₂ with high energy density and high working voltage was developed. The PANI/TiO₂ composite electrode for use as the capacitor cathode was prepared by in situ electrochemical polymerization of aniline in porous anodic titania nanotube arrays on titanium foil substrates. The composite electrode showed good rate capability with a specific capacitance of 10.0 mF·cm^-2 and a high power density of 0.55 mW·cm^-2. Using a dielectric coated anode electrode, the single-cell hybrid capacitor could withstand working voltages as high as 100 V. As the PANI/TiO₂ composite cathode only requires a small volume because of its high specific capacitance, available space can be used to enlarge the anode electrode, leading to an increase in specific capacitance of the hybrid capacitor. The hybrid capacitor had high volumetric and gravimetric energy densities, which were about four times and three times higher than those of a tantalum electrolytic capacitor. The short circuit charge-discharge cycle test for the hybrid capacitor at 100 V showed that its capacitance did not decrease, and the equivalent series resistance did not increase after 10000 cycles, indicating excellent cycle stability and power performance. The peak power density was estimated to be 847.5 W·g^-1. In addition, electrochemical impedance spectroscopy data indicated that the hybrid capacitor had good impedance and frequency characteristics.

Key words: Hybrid capacitor, Electrochemical capacitor, TiO₂, Polyaniline, Tantalum electrolytic capacitor

YANG Bin, WU Hui, HU Song-Wei, LÜ Hui-Ling, SONG Ye, ZHU Xu-Fei. Fabrication and Performance of Electrolytic-Electrochemical Hybrid Capacitors[J]. Acta Phys. -Chim. Sin. 2013, 29(05), 1013-1020. doi: 10.3866/PKU.WHXB201303122

References

(1) Conway, B. E. Electrochemical Supercapacitors, 1st ed.; KluwerAcademic Publishing/Plenum Publisher: New York, 1999; pp11-30.
(2) Burke, A. J. Power Sources 2000, 91, 37. doi: 10.1016/S0378-7753(00)00485-7
(3) Wu, Q.; Xu, Y.; Yao, Z.; Liu, A.; Shi, G. ACS Nano 2010, 4,1963. doi: 10.1021/nn1000035
(4) Yang, X.; Zhu, J.; Qiu, L.; Li, D. Adv. Mater. 2011, 23, 2833.doi: 10.1016/S0378-7753(00)00485-7
(3) Wu, Q.; Xu, Y.; Yao, Z.; Liu, A.; Shi, G. ACS Nano 2010, 4,1963. doi: 10.1021/nn1000035
(4) Yang, X.; Zhu, J.; Qiu, L.; Li, D. Adv. Mater. 2011, 23, 2833.
(5) Zhu, J. B.; Xu, Y. L.;Wang, J.;Wang, J. P. Acta Phys. -Chim.Sin. 2012, 28 (2), 373. [朱剑波, 徐友龙, 王杰, 王景平.物理化学学报, 2012, 28 (2), 373.] doi: 10.3866/PKU.WHXB201112021
(6) Zhu, Y.; Murali, S.; Stoller, M. D.; Ganesh, K. J.; Cai,W.;Ferreira, P. J.; Pirkle, A.;Wallace, R. M.; Cychosz, K. A.;Thommes, M.; Su, D.; Stach, E. A.; Ruoff, R. S. Science 2011,332, 1537. doi: 10.1126/science.1200770
(7) Yang, H. S.; Zhou, X.; Zhang, Q.W. Acta Phys. -Chim. Sin.2005, 21 (4), 414. [杨红生, 周啸, 张庆武. 物理化学学报,2005, 21 (4), 414.] doi: 10.3866/PKU.WHXB20050414
(8) Evans, D. A. High Energy Density Electrolytic-ElectrochemicalHybrid Capacitor. http://www.evanscap.com/pdf/carts14.pdf." target=_blank>10.3866/PKU.WHXB201112021
(6) Zhu, Y.; Murali, S.; Stoller, M. D.; Ganesh, K. J.; Cai,W.;Ferreira, P. J.; Pirkle, A.;Wallace, R. M.; Cychosz, K. A.;Thommes, M.; Su, D.; Stach, E. A.; Ruoff, R. S. Science 2011,332, 1537. doi: 10.1126/science.1200770
(7) Yang, H. S.; Zhou, X.; Zhang, Q.W. Acta Phys. -Chim. Sin.2005, 21 (4), 414. [杨红生, 周啸, 张庆武. 物理化学学报,2005, 21 (4), 414.] doi: 10.3866/PKU.WHXB20050414
(8) Evans, D. A. High Energy Density Electrolytic-ElectrochemicalHybrid Capacitor. http://www.evanscap.com/pdf/carts14.pdf.
(9) Jun, Y.; Park, J. H.; Kang, M. G. Chem. Commun. 2012, 48,6456. doi: 10.1039/c2cc30733b
(10) Wang, D. A.; Liu, Y.;Wang, C.W.; Zhou, F. Prog. Chem. 2010,22 (6), 1035. [王道爱, 刘盈, 王成伟, 周峰. 化学进展,2010, 22 (6), 1035.]doi: 10.1039/c2cc30733b
(10) Wang, D. A.; Liu, Y.;Wang, C.W.; Zhou, F. Prog. Chem. 2010,22 (6), 1035. [王道爱, 刘盈, 王成伟, 周峰. 化学进展,2010, 22 (6), 1035.]
(11) Zhu, X. F.; Han, H.; Song, Y.; Duan,W. Q. Acta Phys. -Chim.Sin. 2012, 28 (6), 1291. [朱绪飞, 韩华, 宋晔, 段文强.物理化学学报, 2012, 28 (6), 1291.] doi: 10.3866/PKU.WHXB201204093
(12) Xie, K. Y.; Li, J.; Lai, Y. Q.; Zhang, Z. A.; Liu, Y. X.; Zhang, G.G.; Huang, H. T. Nanoscale 2011, 3, 2202. doi: 10.1039/c0nr00899k
(13) Han, S. C.; Doh, J. M.; Yoon, J. K.; Kim, G. H.; Byun, J. Y.;Han, S. H.; Hong, K. T.; Kwun, S. I. Met. Mater. Int. 2009, 15 (3), 493. doi: 10.1007/s12540-009-0493-x
(14) Yu, Q. Q.; Chu, C. L.; Lin, P. H.; Sheng, X. B.; Guo, C.; Dong,Y. S. Rare Metal Mat. Eng. 2011, 40 (Suppl.2), 201. [余青青,储成林, 林萍华, 盛晓波, 郭超, 董寅生. 稀有金属材料与工程, 2011, 40 (Suppl.2), 201.]" target=_blank>10.3866/PKU.WHXB201204093
(12) Xie, K. Y.; Li, J.; Lai, Y. Q.; Zhang, Z. A.; Liu, Y. X.; Zhang, G.G.; Huang, H. T. Nanoscale 2011, 3, 2202. doi: 10.1039/c0nr00899k
(13) Han, S. C.; Doh, J. M.; Yoon, J. K.; Kim, G. H.; Byun, J. Y.;Han, S. H.; Hong, K. T.; Kwun, S. I. Met. Mater. Int. 2009, 15 (3), 493. doi: 10.1007/s12540-009-0493-x
(14) Yu, Q. Q.; Chu, C. L.; Lin, P. H.; Sheng, X. B.; Guo, C.; Dong,Y. S. Rare Metal Mat. Eng. 2011, 40 (Suppl.2), 201. [余青青,储成林, 林萍华, 盛晓波, 郭超, 董寅生. 稀有金属材料与工程, 2011, 40 (Suppl.2), 201.]
(15) Ma, L.; Tang, Q. Journal of Chongqing University (NaturalScience Edition) 2002, 25 (2), 124. [马利, 汤琪. 重庆大学学报(自然科学版), 2002, 25 (2), 124.]
(16) Prasad, K. R.; Munichandraiah, N. J. Power Sources 2002, 112,443.
(17) Huang,W. S.; Humphrey, B. D.; MacDiarmid, A. G. J. Chem.Soc. Faraday Trans. I 1986, 82, 2385.
(18) Arico, A. S.; Bruce, P.; Scrosati, B.; Tarascon, J. M.; vanSchalkwijk,W. Nat. Mater. 2005, 4, 366. doi: 10.1038/nmat1368
(19) Cho, S. I.; Lee, S. B. Accounts Chem. Res. 2008, 41 (6), 699.doi: 10.1021/ar7002094
(20) Zhang, Q. Q.; Li, Y.; Feng, Y. Y.; Feng,W. Electrochim. Acta2013, 90, 95. doi: 10.1016/j.electacta.2012.11.035
(21) Tian, S. J.; Baba, A.; Liu, J. Y.;Wang, Z. H.; Knoll,W.; Park, M.K.; Advincula, R. Adv. Funct. Mater. 2003, 13, 473. doi: 10.1002/adfm.200304320
(22) Zhong, H. X.; Zhao, C. B.; Luo, H.; Zhang, L. Z. ActaPhys. -Chim. Sin. 2012, 28 (11), 2641. [仲皓想, 赵春宝,骆浩, 张灵志. 物理化学学报, 2012, 28 (11), 2641.]doi: 10.3866/PKU.WHXB201207181
(23) Dhawale, D. S.; Vinub, A.; Lokhandea, C. D. Electrochim. Acta2011, 56, 9482. doi: 10.1016/j.electacta.2011.08.042
(24) Pud, A. A. Synth. Met. 1994, 66, 1. doi: 10.1016/0379-6779(94)90155-4
(25) Zhang, L. Y.; Yao, X. Dielectric Physics; Xi'an Jiao TongUniversity Press: Xi'an, 1991; pp 193-221. [张良莹, 姚熹.电介质物理. 西安: 西安交通大学出版社, 1991: 193-221.]" target=_blank>10.1038/nmat1368
(19) Cho, S. I.; Lee, S. B. Accounts Chem. Res. 2008, 41 (6), 699.doi: 10.1021/ar7002094
(20) Zhang, Q. Q.; Li, Y.; Feng, Y. Y.; Feng,W. Electrochim. Acta2013, 90, 95. doi: 10.1016/j.electacta.2012.11.035
(21) Tian, S. J.; Baba, A.; Liu, J. Y.;Wang, Z. H.; Knoll,W.; Park, M.K.; Advincula, R. Adv. Funct. Mater. 2003, 13, 473. doi: 10.1002/adfm.200304320
(22) Zhong, H. X.; Zhao, C. B.; Luo, H.; Zhang, L. Z. ActaPhys. -Chim. Sin. 2012, 28 (11), 2641. [仲皓想, 赵春宝,骆浩, 张灵志. 物理化学学报, 2012, 28 (11), 2641.]doi: 10.3866/PKU.WHXB201207181
(23) Dhawale, D. S.; Vinub, A.; Lokhandea, C. D. Electrochim. Acta2011, 56, 9482. doi: 10.1016/j.electacta.2011.08.042
(24) Pud, A. A. Synth. Met. 1994, 66, 1. doi: 10.1016/0379-6779(94)90155-4
(25) Zhang, L. Y.; Yao, X. Dielectric Physics; Xi'an Jiao TongUniversity Press: Xi'an, 1991; pp 193-221. [张良莹, 姚熹.电介质物理. 西安: 西安交通大学出版社, 1991: 193-221.]
(26) Chang, T. Y.;Wang, X.; Evans, D. A.; Robinson, S. L.; Zheng, J.P. J. Power Sources 2002, 110, 138.
(27) Sherrill, S. A.; Banerjee, P.; Rubloff, G.W.; Lee, S. B. Phys.Chem. Chem. Phys. 2011, 13, 20714.

[1]	Ganyin Yuan, Zheng Xi, Chu Wang, Xiaohuan Sun, Jie Han, Rong Guo. Construction of Supramolecular Chiral Polyaniline-Gold Nanocomposite as Nanozyme for Enantioselective Catalysis [J]. Acta Phys. -Chim. Sin., 2023, 39(7): 2212061-0.
[2]	Na Lu, Xuedong Jing, Yao Xu, Wei Lu, Kuichao Liu, Zhenyi Zhang. Effective Cascade Modulation of Charge-Carrier Kinetics in the Well-Designed Multi-Component Nanofiber System for Highly-Efficient Photocatalytic Hydrogen Generation [J]. Acta Phys. -Chim. Sin., 2023, 39(4): 2207045-0.
[3]	Yue Yang, Jiawei Zhu, Pengyan Wang, Haimi Liu, Weihao Zeng, Lei Chen, Zhixiang Chen, Shichun Mu. NH₂-MIL-125 (Ti) Derived Flower-Like Fine TiO₂ Nanoparticles Implanted in N-doped Porous Carbon as an Anode with High Activity and Long Cycle Life for Lithium-Ion Batteries [J]. Acta Phys. -Chim. Sin., 2022, 38(6): 2106002-.
[4]	Hongsa Han, Yanqing Wang, Yunlong Zhang, Yuanyuan Cong, Jiaqi Qin, Rui Gao, Chunxiao Chai, Yujiang Song. Oxygen Reduction Reaction Electrocatalysts Derived from Metalloporphyrin-Modified Meso-/Macroporous Polyaniline [J]. Acta Phys. -Chim. Sin., 2021, 37(9): 2008017-.
[5]	Yi Zhou, Weilong Ouyang, Yuejun Wang, Haiqiang Wang, Zhongbiao Wu. Core-Shell Structured NH₂-UiO-66@TiO₂ Photocatalyst for the Degradation of Toluene under Visible Light Irradiation [J]. Acta Phys. -Chim. Sin., 2021, 37(8): 2009045-.
[6]	Ping Wang, Haitao Li, Yanjie Cao, Huogen Yu. Carboxyl-Functionalized Graphene for Highly Efficient H₂-Evolution Activity of TiO₂ Photocatalyst [J]. Acta Phys. -Chim. Sin., 2021, 37(6): 2008047-.
[7]	Jiabi Li, Xi Wu, Shengwei Liu. Fluorinated TiO₂ Hollow Photocatalysts for Photocatalytic Applications [J]. Acta Phys. -Chim. Sin., 2021, 37(6): 2009038-.
[8]	Zihui Mei, Guohong Wang, Suding Yan, Juan Wang. Rapid Microwave-Assisted Synthesis of 2D/1D ZnIn₂S₄/TiO₂ S-Scheme Heterojunction for Catalyzing Photocatalytic Hydrogen Evolution [J]. Acta Phys. -Chim. Sin., 2021, 37(6): 2009097-.
[9]	Piao Jin, Zichao Guan, Yan Liang, Kai Tan, Xia Wang, Guangling Song, Ronggui Du. Photocathodic Protection on Stainless Steel by Heterostructured NiO/TiO₂ Nanotube Array Film with Charge Storage Capability [J]. Acta Phys. -Chim. Sin., 2021, 37(3): 1906033-.
[10]	Yuhong Li,Xin-Ping Wu,Cong Liu,Meng Wang,Benteng Song,Guiyun Yu,Gang Yang,Wenhua Hou,Xue-Qing Gong,Luming Peng. NMR and EPR Studies of Partially Reduced TiO₂ [J]. Acta Physico-Chimica Sinica, 2020, 36(4): 1905021-.
[11]	Shuhua Duan,Shufeng Wu,Lei Wang,Houde She,Jingwei Huang,Qizhao Wang. Rod-Shaped Metal Organic Framework Structured PCN-222(Cu)/TiO₂ Composites for Efficient Photocatalytic CO₂ Reduction [J]. Acta Physico-Chimica Sinica, 2020, 36(3): 1905086-.
[12]	Pan Zhao,Bingjun Yang,Jiangtao Chen,Junwei Lang,Tianyun Zhang,Xingbin Yan. A Safe, High-Performance, and Long-Cycle Life Zinc-Ion Hybrid Capacitor Based on Three-Dimensional Porous Activated Carbon [J]. Acta Physico-Chimica Sinica, 2020, 36(2): 1904050-.
[13]	Fei CHENG,Jian YANG,Liang YAN,Jun ZHAO,Huahua ZHAO,Huanling SONG,Lingjun CHOU. Influence of the Composition/Texture of Solid Acid WO₃/TiO₂-Supported Lithium-Manganese Catalysts on the Oxidative Coupling of Methane [J]. Acta Physico-Chimica Sinica, 2019, 35(9): 1027-1036.
[14]	Jiawei ZHANG, Sheng WANG, Fusheng LIU, Xiaojie FU, Guoquan MA, Meishun HOU, Zhuo TANG. Preparation of Defective TiO₂_-x Hollow Microspheres for Photocatalytic Degradation of Methylene Blue [J]. Acta Physico-Chimica Sinica, 2019, 35(8): 885-895.
[15]	Cheng GONG,Siwan XIANG,Zeyang ZHANG,Lan SUN,Chenqing YE,Changjian LIN. Construction and Visible-Light-Driven Photocatalytic Properties of LaCoO₃-TiO₂ Nanotube Arrays [J]. Acta Physico-Chimica Sinica, 2019, 35(6): 616-623.

Fabrication and Performance of Electrolytic-Electrochemical Hybrid Capacitors

PDF

Like

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Metrics

Recommended 0