双钙钛矿La2CoNiO6无机纳米纤维的制备及超级电容器性能

doi:10.3866/PKU.WHXB201412164

Abstract

Abstract:

A La₂CoNiO₆ inorganic nanofiber supercapacitor electrode material was successfully prepared from a polyvinylpyrrolidone/lanthanum nitrate-cobalt acetate-nickel acetate (PVP/LCN) precursor by electrostatic spinning. Its surface morphology and structure were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), and transmission electron microscopy (TEM). We found that the fibers were connected through rhombohedral La₂CoNiO₆ nanoparticles resulting in a linear spatial network structure. The electrochemical performance of the as-prepared inorganic nanofibers was characterized by cyclic voltammetry (CV), chronopotentiograms (CP), and cycle life tests. The results show that the La₂CoNiO₆ nanofiber electrode material has good capacitor performance. For the three-electrode system the electrode achieved a respectable specific capacitance of 335.0 F·g^-1 at 0.25 A·g^-1. For the symmetrical two-electrode system the electrode achieved a specific capacitance of 129.1 F·g^-1 at the same current density.

Key words: Double-perovskite, Electrostatic spinning, Inorganic nanofiber, Supercapacitor, Electrode material

WU Yan-Bo, BI Jun, WEI Bin-Bin. Preparation and Supercapacitor Properties of Double-Perovskite La₂CoNiO₆ Inorganic Nanofibers[J]. Acta Phys. -Chim. Sin. 2015, 31(2), 315-321. doi: 10.3866/PKU.WHXB201412164

References

(1) Xu, L. L.; Zhang, X. H.; Chen, J. H. Acta Phys. -Chim. Sin. 2014, 30 (7), 1274. [徐玲玲, 张小华, 陈金华. 物理化学学报, 2014, 30 (7), 1274.] doi: 10.3866/PKU.WHXB201405044
(2) Wu, H. Y.;Wang, H.W. Acta Phys. -Chim. Sin. 2013, 29 (7), 1501. [吴红英, 王欢文. 物理化学学报, 2013, 29 (7), 1501.] doi: 10.3866/PKU.WHXB201304241
(3) Baran, E. J. Catal. Today 1990, 8 (2), 133. doi: 10.1016/0920-5861(90)87015-U
(4) Vailionis, A.; Boschker, H.; Siemons,W.; Houwman, E. P.; Blank, D. H. A.; Rijnders, G.; Koster, G. Phys. Rev. B 2011, 83(6), 064101.
(5) Baek, S.W.; Kim, J. H.; Bae, J. Solid State Ionics 2008, 179 (27-32), 1570. doi: 10.1016/j.ssi.2007.12.010
(6) Li, Z. F.; Li, G. B.; Sun, J. L.;Wang, Y. X.; You, L. P.; Lin, J. H. Solid State Sci. 2006, 8 (9), 1035. doi: 10.1016/j.solidstatesciences.2005.12.015
(7) Sleight, A.W.; Longo, J.;Ward, R. Inorg. Chem. 1962, 1 (2), 245. doi: 10.1021/ic50002a010
(8) Regaieg, Y.; Delaizir, G.; Herbst, F.; Sicard, L.; Monnier, J.; Montero, D.; Villeroy, B.; Ammar-Merah, S.; Cheikhrouhou, A.; Godart, C.; Koubaa, M. Mater. Lett. 2012, 80, 195. doi: 10.1016/j.matlet.2012.04.046
(9) Rajendran, D. N.; Ravindran Nair, K.; Prabhakar Rao, P.; Sibi, K. S.; Koshy, P.; Vaidyan, V. K. Mater. Lett. 2008, 62 (4), 623.
(10) Suntivich, J.; Gasteiger, H. A.; Yabuuchi, N.; Nakanishi, H.; Goodenough, J. B.; Shao-Horn, Y. Nat. Chem. 2011, 3 (7), 546. doi: 10.1038/nchem.1069
(11) Sarma, D. D.; Shanthi, N.; Barman, S. R. Phys. Rev. Lett. 1995, 75 (6), 1126. doi: 10.1103/PhysRevLett.75.1126
(12) Lin, Y. Q.; Chen, X. M.; Liu, X. Q. Solid State Commun. 2009, 149 (19), 784.
(13) Singh, M. P.; Truong, K. D.; Fournier, P. Appl. Phys. Lett. 2007, 91 (4), 042504. doi: 10.1063/1.2762292
(14) Marrero-López, D.; Pena-Martinez, J.; Ruiz-Morales, J. C.; Pérez-Coll, D.; Aranda, M. A. G.; Núñez, P. Mater. Res. Bull. 2008, 43 (8), 2441.
(15) Fan, H. J.;Werner, P.; Zacharias, M. Small 2006, 2 (6), 700.
(16) Kodambaka, S.; Tersoff, J.; Reuter, M. C.; Ross, F. M. Science 2007, 316 (5825), 729. doi: 10.1126/science.1139105
(17) Hsu, M. C.; Leu, I. C.; Sun, Y. M.; Hon, M. H. J. Solid State Chem. 2006, 179 (5), 1421. doi: 10.1016/j.jssc.2006.01.077
(18) Leng, J.; Li, S.;Wang, Z. S.; Xue, Y. F.; Xu, D. P. Mater. Lett. 2010, 64 (17), 1912. doi: 10.1016/j.matlet.2010.06.005
(19) Yuh, J.; Nino, J. C.; Sigmund,W. M. Mater. Lett. 2005, 59 (28), 3645. doi: 10.1016/j.matlet.2005.07.008
(20) Chen, C. Q.; Li,W.; Cao, C. Y.; Song,W. G. J. Mater. Chem. 2010, 20 (33), 6968. doi: 10.1039/c0jm01320j
(21) Hwang, D. K.; Kim, S.; Lee, J. H.; Hwang, I. S.; Kim, I. D. J. Mater. Chem. 2011, 21 (6), 1959. doi: 10.1039/c0jm02256j
(22) Khomenko, V.; Frackowiak, E.; Beguin, F. Electrochim. Acta 2005, 50 (12), 2499. doi: 10.1016/j.electacta.2004.10.078
(23) Stoller, M. D.; Ruoff, R. S. Energy Environ. Sci. 2010, 3 (9), 1294. doi: 10.1039/c0ee00074d
(24) Stoller, M. D.; Park, S.; Zhu, Y.W.; An, J.; Ruoff, R. S. Nano Lett. 2008, 8 (10), 3498. doi: 10.1021/nl802558y
(25) Zhang, X. B.; Chen, M. H.; Zhang, X. G.; Li, Q.W. Acta Phys. -Chim. Sin. 2010, 26 (12), 3169. [张校菠, 陈名海, 张校刚, 李清文. 物理化学学报, 2010, 26 (12), 3169.] doi: 10.3866/PKU.WHXB20101203
(26) Li, Y. H.; Huang, K. L.; Yao, Z. F.; Liu, S. Q.; Qing, X. X. Electrochim. Acta 2011, 56 (5), 2140. doi: 10.1016/j.electacta.2010.11.074
(27) Yuan, C. Z.; Xiong, S. L.; Zhang, X. G.; Shen, L. F.; Zhang, F.; Gao, B.; Su, L. H. Nano Res. 2009, 2 (9), 722. doi: 10.1007/s12274-009-9079-7
(28) Kim, G.;Wang, S.; Jacobson, A. J.; Reimus, L.; Brodersenb, P.; Mims, C. A. J. Mater. Chem. 2007, 17 (24), 2500. doi: 10.1039/b618345j
(29) Taskin, A. A.; Lavrov, A. N.; Ando, Y. Appl. Phys. Lett. 2005, 86(9), 091910. doi: 10.1063/1.1864244
(30) Maignan, A.; Martin, C.; Pelloquin, D.; Nguyen, N.; Raveau, B. J. Solid State Chem. 1999, 142 (2), 247. doi: 10.1006/jssc.1998.7934

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Preparation and Supercapacitor Properties of Double-Perovskite La₂CoNiO₆ Inorganic Nanofibers

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Preparation and Supercapacitor Properties of Double-Perovskite La2CoNiO6 Inorganic Nanofibers

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Preparation and Supercapacitor Properties of Double-Perovskite La₂CoNiO₆ Inorganic Nanofibers