物理化学学报 >> 2003, Vol. 19 >> Issue (12): 1159-1162.doi: 10.3866/PKU.WHXB20031214

研究简报 上一篇    下一篇

纳米AgBr/PMMA光致变色杂化材料制备与表征

董相廷;何颖;闫景辉;薛勃飞;冯秀丽;洪广言   

  1. 长春理工大学材料与化工学院,长春　130022; 中国科学院长春应用化学研究所,长春　130022
  • 收稿日期:2003-04-15 修回日期:2003-08-03 发布日期:2003-12-15
  • 通讯作者: 董相廷 E-mail:xtdong888@sohu.com

Preparation and Characterization of Nanosized AgBr/PMMA Photochromic Hybrid Material

Dong Xiang-Ting;He Ying;Yan Jing-Hui;Xue Bo-Fei;Feng Xiu-Li;Hong Guang-Yan   

  1. College of Materials and Chemical Engineering, Changchun University of Science and Technology, Changchun　130022;Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun　130022
  • Received:2003-04-15 Revised:2003-08-03 Published:2003-12-15
  • Contact: Dong Xiang-Ting E-mail:xtdong888@sohu.com

PDF

3556

赞

摘要： 采用本体聚合法制备了纳米AgBr/PMMA(聚甲基丙烯酸甲酯)光致变色杂化材料. XRD分析表明，纳米AgBr/PMMA杂化材料是无定形的. SEM分析表明， AgBr含量不同，杂化材料的断面形貌明显不同，随AgBr含量的增加，杂化材料由韧性断裂向脆性断裂转变. EDS面分析表明， Ag、Br元素在杂化材料中均匀分布.所制备的纳米AgBr/PMMA杂化材料具有一定的光致变色效应.

关键词: AgBr, 聚甲基丙烯酸甲酯(PMMA), 纳米材料, 杂化材料, 光致变色

Abstract: Nanosized AgBr/PMMA hybrid material of photochromism was synthesized byin situ polymerization. XRD analyses indicate that the nanosized AgBr/PMMA hybrid materials are amorphous. SEM analyses show that the morphology of the hybrid material varies with the AgBr content in the hybrid materials, and the tenacity fracture of the hybrid material changes into fragility fracture with the increase of AgBr content. EDS reveals that the distributions of both elements of Ag and Br in the hybrid material are homogeneous. The nanosized AgBr/PMMA hybrid material has a photochromic effect.

Key words: AgBr, PMMA(polymethylmethacrylate), Nanomaterial, Hybrid material, 　Photochromism