物理化学学报 >> 2000, Vol. 16 >> Issue (09): 776-778.doi: 10.3866/PKU.WHXB20000903

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时间分辨红外发射光谱研究C2H3+NO反应体系

冯文辉, 王宝山, 王惠, 孔繁敖   

  1. 中国科学院化学研究所，北京 100080
  • 收稿日期:2000-05-23 修回日期:2000-06-21 发布日期:2000-09-15
  • 通讯作者: 孔繁敖 E-mail:kong@mrdlab.icas.ac.cn

Reaction of C2H3+NO Studied by Time-Resolved Emission Spectroscopy

Feng Wen-Hui, Wang Bao-Shan, Wang Hui, Kong Fan-Ao   

  1. Institute of Chemistry,Chinese Academy of Sciences,Beijing 100080
  • Received:2000-05-23 Revised:2000-06-21 Published:2000-09-15
  • Contact: Kong Fan-Ao E-mail:kong@mrdlab.icas.ac.cn

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关键词: NO, C2H3, 反应, FTIR

Abstract:

The elementary reaction of C2H3＋ NO has been reported for the first time in this paper.C2H3 radical was produced by laser photolysis of vinyl bromide at 248 nm. Vibrationally excited reaction products H2CO,NCO and HCN were observed. Two exothermic reaction channels leading to HCN＋ H2CO and CH3＋ NCO are identified.

Key words: NO, C2H3, Reaction, FTIR