NiS-Ni3S2树状异质结阵列在析氧反应中的应用

doi:10.3866/PKU.WHXB201804022

物理化学学报 >> 2018, Vol. 34 >> Issue (12): 1397-1404.doi: 10.3866/PKU.WHXB201804022

所属专题：表面物理化学

NiS-Ni₃S₂树状异质结阵列在析氧反应中的应用

罗盼,孙芳,邓菊,许海涛,张慧娟*(),王煜*()

重庆大学化学化工学院，输配电装备及系统安全与新技术国家重点实验室，重庆 400044

收稿日期:2018-03-08 发布日期:2018-04-27
通讯作者: 张慧娟,王煜 E-mail:zhanghj@cqu.edu.cn;wangy@cqu.edu.cn
基金资助:
中央高校基本科研业务费(0301005202017);中组部青年千人计划(0220002102003);国家自然科学基金(21373280);国家自然科学基金(21403019);北京分子科学国家实验室;重庆大学百人计划(0903005203205);机械传动国家重点实验室(SKLMT-ZZKT-2017M11)

Tree-Like NiS-Ni₃S₂/NF Heterostructure Array and Its Application in Oxygen Evolution Reaction

Pan LUO,Fang SUN,Ju DENG,Haitao XU,Huijuan ZHANG*(),Yu WANG*()

The State Key Laboratory of Power Transmission Equipment and System Security, School of Chemistry and Chemical Engineering, Chongqing University, Chongqing 400044, P. R. China

Received:2018-03-08 Published:2018-04-27
Contact: Huijuan ZHANG,Yu WANG E-mail:zhanghj@cqu.edu.cn;wangy@cqu.edu.cn
Supported by:
the Fundamental Research Funds for the Central Universities, China(0301005202017);the Thousand Young Talents Program of the Chinese Central Government(0220002102003);the National Natural Science Foundation of China(21373280);the National Natural Science Foundation of China(21403019);the Beijing National Laboratory for Molecular Sciences, China;the Hundred Talents Program at Chongqing University, China(0903005203205);the State Key Laboratory of Mechanical Transmissions Project, China(SKLMT-ZZKT-2017M11)

摘要/Abstract

摘要：

在过去的几十年里，数以万计化石能源的开发和利用导致了一系列的环境问题，例如温室效应和水污染等。许多应对的策略被提出以应对环境问题，可再生氢气是其中一个最为瞩目的能源。而在其中，电解水是为了获得可在生氢气最为环保的方案。在阳极发生反应过于低效则限制着这项技术的发展，所以研究开发高效的阳极电催化剂变得尤为重要。在本文中，我们通过一步水热法合成了一种直接生长在泡沫镍基地的NiS-Ni₃S₂树状异质结阵列。这个材料在实际电解水的阳极反应中表现出巨大的潜能，表现出高效的电催化性能和超强的稳定性能。NiS-Ni₃S₂树状异质结阵列比纳米棒状Ni₃S₂表现出更好的性能。因为其拥有更高的比表面积和NiS-Ni₃S₂之间协同效应展现。NiS-Ni₃S₂树状异质结阵列的高性能也可能是因为其紧密地与泡沫镍基地连接，拥有较好的电子传输路径。同时，在反应的过程中，一些羟基氢氧化镍的产生也有利于催化效果的提升。毫无疑问，NiS-Ni₃S₂树状异质结阵列作为电解水的阳极催化剂拥有极大的前景。

关键词: 异质结结构, 树状整列, NiS-Ni₃S₂, 析氧反应

Abstract:

In the past decade, fossil fuel resources have been exploited and utilized extensively, which could lead to increasing environmental crises, like greenhouse effect, water pollution, etc. Accordingly, many coping strategies have been put forward, such as water electrolysis, metal-air batteries, fuel cell, etc. Among the strategies mentioned above, water electrolysis is one of the most promising. Water splitting, which can achieve sustainable hydrogen production, is a favorable strategy due to the abundance of water resources. Splitting of water includes two half reactions integral to its operation: hydrogen evolution reaction (HER) and oxygen evolution reaction (OER). However, its practical application is mainly impeded by the sluggish anode reaction. Simultaneously, noble metal oxides (IrO₂ and RuO₂) and Pt-based catalysts have been recognized as typical OER catalysts; however, the scarcity of noble metals greatly limits their development. Hence, designing an alternative electrocatalyst plays a vital role in the development of OER. However, exploring a highly active electrocatalyst for OER is still difficult. Herein, a miraculous construction of a tree-like array of NiS/Ni₃S₂ heterostructure, which is directly grown on Ni foam substrate, is synthesized via one-step hydrothermal process. Since NiS and Ni₃S₂ have shown great OER performance in previous investigations, this novel NiS-Ni₃S₂/Nikel foam (NF) heterostructure array has tremendous potential as a practical OER catalyst. Upon application in OER, the NiS-Ni₃S₂/NF heterostructure array catalyst exhibits excellent activity and stability. More specifically, this novel tree-like NiS-Ni₃S₂ heterostructure array shows extremely low overpotential (269 mV to achieve a current density of 10 mA·cm^-2) and small Tafel slope for OER. It also shows extraordinary stability in alkaline electrolytes. Compared with the Ni₃S₂ nanorods array, the NiS-Ni₃S₂ heterostructure array has a synergistic effect that can improve the OER performance. Due to the secondary structure (Ni₃S₂ nanosheets), the tree-like NiS-Ni₃S₂ array provides more active sites could have higher specific surface area. The greater activity of the NiS/Ni₃S₂ heterostructure may also stem from the tight conjunction between tree-like NiS/Ni₃S₂ and the Ni foam substrate, which is beneficial for electronic transmission. Hydroxy groups can accumulate in large amounts on the surface of the tree-like array, and it also generates some Ni-based oxides that are favorable to OER. Moreover, the synergistic effect of such heterostructure can intrinsically improve the OER activity. The unique tree-like NiS-Ni₃S₂ heterostructure array has great potential as an alternative OER electrocatalyst.

Key words: Heterostructure, Tree-like array, NiS-Ni₃S₂, Oxygen evolution reaction

点击下载补充材料PDF格式文件

罗盼,孙芳,邓菊,许海涛,张慧娟,王煜. NiS-Ni₃S₂树状异质结阵列在析氧反应中的应用[J]. 物理化学学报, 2018, 34(12), 1397-1404. doi: 10.3866/PKU.WHXB201804022

Pan LUO,Fang SUN,Ju DENG,Haitao XU,Huijuan ZHANG,Yu WANG. Tree-Like NiS-Ni₃S₂/NF Heterostructure Array and Its Application in Oxygen Evolution Reaction[J]. Acta Phys. -Chim. Sin. 2018, 34(12), 1397-1404. doi: 10.3866/PKU.WHXB201804022

链接本文: https://www.whxb.pku.edu.cn/CN/10.3866/PKU.WHXB201804022

https://www.whxb.pku.edu.cn/CN/Y2018/V34/I12/1397

参考文献

1	Wang F. ; Shifa T. A. ; Zhan X. ; Huang Y. ; Liu K. ; Cheng Z. ; Jiang C. ; He J. Nanoscale 2015, 7 (47), 19764.
2	Yan Y. ; Xia B. Y. ; Zhao B. ; Wang X. J. Mater. Chem. A 2016, 4 (45), 17587.
3	Gao M. R. ; Xu Y. F. ; Jiang J. ; Yu S. H. Chem. Soc. Rev. 2013, 42 (7), 2986.
4	Zhou W. ; Wu X. J. ; Cao X. ; Huang X. ; Tan C. ; Tian J. ; Liu H. ; Wang J. ; Zhang H. Energy Environ. Sci. 2013, 6 (10), 2921.
5	Dou Y. H. ; Liao T. ; Ma Z. Q. ; Tian D. L. ; Liu Q. N. ; Xiao F. ; Sun Z. Q. ; Kim J. H. ; Dou S. X. Nano Energy 2016, 30, 267.
6	Jin C. ; Lu F. L. ; Cao X. C. ; Yang Z. R. ; Yang R. Z. J. Mater. Chem. A 2013, 1 (39), 12170.
7	Cheng N. ; Liu Q. ; Tian J. ; Sun X. ; He Y. ; Zhai S. ; Asiri A. M. Int. J. Hydrog. Energy 2015, 40 (32), 9866.
8	Dong B. ; Zhao X. ; Han G. Q. ; Li X. ; Shang X. ; Liu Y. R. ; Hu W. H. ; Chai Y. M. ; Zhao H. ; Liu C. G. J. Mater. Chem. A 2016, 4 (35), 13499.
9	Liang H. ; Meng F. ; Cabán-Acevedo M. ; Li L. ; Forticaux A. ; Xiu L. ; Wang Z. ; Jin S. Nano Lett. 2015, 15 (2), 1421.
10	Gao M. R. ; Cao X. ; Gao Q. ; Xu Y. F. ; Zheng Y. R. ; Jiang J. ; Yu S. H. ACS Nano 2014, 8 (4), 3970.
11	Swesi A. T. ; Masud J. ; Nath M. Energy Environ. Sci. 2016, 9 (5), 1771.
12	Chen J. S. ; Ren J. ; Shalom M. ; Fellinger T. ; Antonietti M. ACS Appl. Mater. Interfaces 2016, 8 (8), 5509.
13	Chen P. Z. ; Xu K. ; Tong Y. ; Li X. L. ; Tao S. ; Fang Z. W. ; Chu W. S. ; Wu X. J. ; Wu C. Z. Inorg. Chem. Front. 2016, 3 (2), 236.
14	Yang L. ; Gao M. G. ; Dai B. ; Guo X. H. ; Liu Z. Y. ; Peng B. H. Electrochim. Acta 2016, 191, 813.
15	Li T. T. ; Zuo Y. P. ; Lei X. M. ; Li N. ; Liu J. W. ; Han H. Y. J. Mater. Chem. A 2016, 4 (21), 8029.
16	Zhang Z. ; Zhao H. ; Xia Q. ; Allen J. ; Zeng Z. ; Gao C. ; Li Z. ; Du X. ; ?wierczek K. Electrochim. Acta 2016, 211, 761.
17	Feng L. L. ; Yu G. ; Wu Y. ; Li G. D. ; Li H. ; Sun Y. ; Asefa T. ; Chen W. ; Zou X. J. Am. Chem. Soc. 2015, 137 (44), 14023.
18	Zhou X. ; Liu Y. ; Ju H. ; Pan B. ; Zhu J. ; Ding T. ; Wang C. ; Yang Q. Chem. Mater. 2016, 28 (6), 1838.
19	Zhang J. ; Wang T. ; Pohl D. ; Rellinghaus B. ; Dong R. ; Liu S. ; Zhuang X. ; Feng X. Angew. Chem. Int. Ed. 2016, 55 (23), 6702.
20	Duan X. D. ; Wang C. ; Shaw J. C. ; Cheng R. ; Chen Y. ; Li H. L. ; Wu X. P. ; Tang Y. ; Zhang Q. L. ; Pan A. L. ; et al Nat. Nanotechnol. 2014, 9 (12), 1024.
21	Lee D. K. ; Ahn C. W. ; Jeon H. J. Microelectron. Eng. 2016, 166, 1.
22	Zhao Y. ; Zhang Y. ; Zhao H. ; Li X. ; Li Y. ; Wen L. ; Yan Z. ; Huo Z. Nano Res. 2015, 8 (8), 2763.
23	Jeong Y. U. ; Manthiram A. Inorg. Chem. 2001, 40 (1), 73.
24	Huang S. ; Harris K. D. ; Lopez-Capel E. ; Manning D. A. ; Rickard D. Inorg. Chem. 2009, 48 (24), 11486.
25	Zheng J. ; Zhou W. ; Liu T. ; Liu S. ; Wang C. ; Guo L. Nanoscale 2017, 9 (13), 4409.
26	Xu K. ; Chen P. ; Li X. ; Tong Y. ; Ding H. ; Wu X. ; Chu W. ; Peng Z. ; Wu C. ; Xie Y. J. Am. Chem. Soc. 2015, 137 (12), 4119.
27	Zhu T. ; Zhu L. L. ; Wang J. ; Ho G. W. J. Mater. Chem. A 2016, 4 (36), 13916.

[1]	陈芸, 邓代洁, 徐丽, 朱兴旺, 李赫楠, 孙成明. 共价键调控电荷转移以实现自供能电化学传感平台对重金属离子的灵敏分析[J]. 物理化学学报, 2026, 42(1): 100144 - .
[2]	韩鑫, 程志豪, 张金凤, 刘杰, 钟澄, 胡文彬. 非晶高熵FeCoCrMnBS氢氧化物构筑及其增强氧析出催化性能研究[J]. 物理化学学报, 2025, 41(4): 100033 - .
[3]	秦春玲, 陈爽, GomaaHassanien, ShenashenMohamed A., El-SaftySherif A., 刘倩, 安翠华, 刘熙俊, 邓齐波, 胡宁. 外加物理场调控二维材料的HER和OER性能[J]. 物理化学学报, 2024, 40(9): 2307059 - .
[4]	许文涛, 莫栩妍, 周洋, 翁祖贤, 莫坤玲, 吴炎桦, 蒋欣霖, 李丹, 蓝汤淇, 文欢, 郑伏琴, 樊友军, 陈卫. 双金属浸出诱导催化剂重构用于高活性和高稳定性电化学水氧化[J]. 物理化学学报, 2024, 40(8): 2308003 - .
[5]	冯炜程, 于景成, 杨溢澜, 郭宜阁, 邹庚, 刘晓菊, 陈洲, 董坤, 宋月锋, 汪国雄, 包信和. 调控双钙钛矿中高熵组分促进高温析氧反应[J]. 物理化学学报, 2024, 40(6): 2306013 - .
[6]	邢雅娟, 薛辉, 孙静, 郭念坤, 宋天山, 孙佳雯, 郝翊茹, 王勤. Cu₃P辅助诱导Ni₂P电荷定向转移和表面重构以获得高效析氧活性[J]. 物理化学学报, 2024, 40(3): 2304046 - .
[7]	谢静宜, 吕千喜, 乔韦珍, 卜辰宇, 张昱声, 翟雪君, 吕仁庆, 柴永明, 董斌. 强钴―氧键合作用提升缺陷型Co₂MnO₄酸性析氧反应稳定性[J]. 物理化学学报, 2024, 40(3): 2305021 - .
[8]	白武鑫, 周倩倩, 卢振杰, 宋晔, 付永胜. 碳布负载的钴镍双金属沸石咪唑框架作为独立电极用于高效电催化析氧反应[J]. 物理化学学报, 2024, 40(3): 2305041 - .
[9]	段欣漩, Sendeku Marshet Getaye, 张道明, 周道金, 徐立军, 高学庆, 陈爱兵, 邝允, 孙晓明. 钨掺杂镍铁水滑石高效电催化析氧反应[J]. 物理化学学报, 2024, 40(1): 2303055 - .
[10]	胡荣, 韦丽云, 鲜靖林, 房光钰, 吴植傲, 樊淼, 郭家越, 李青翔, 刘凯思, 姜会钰, 徐卫林, 万骏, 姚永刚. 微波热冲快速制备二维多孔La_0.2Sr_0.8CoO₃钙钛矿用于高效电催化析氧反应[J]. 物理化学学报, 2023, 39(9): 2212025 -0 .
[11]	夏伟锋, 季成宇, 王锐, 裘式纶, 方千荣. 基于四硫富瓦烯的无金属共价有机框架材料用于高效电催化析氧反应[J]. 物理化学学报, 2023, 39(9): 2212057 -0 .
[12]	胡洋, 刘斌, 徐路遥, 董自强, 仵亚婷, 刘杰, 钟澄, 胡文彬. 基于微流控技术平台的Pt基三元电催化剂高通量合成和筛选[J]. 物理化学学报, 2023, 39(3): 2209004 -0 .
[13]	徐斯然, 吴奇, 卢帮安, 唐堂, 张佳楠, 胡劲松. “绿氢”工业化碱性催化剂研究现状及未来展望[J]. 物理化学学报, 2023, 39(2): 2209001 -0 .
[14]	李景学, 于跃, 徐斯然, 闫文付, 木士春, 张佳楠. 电子自旋效应在电催化剂中的作用[J]. 物理化学学报, 2023, 39(12): 2302049 - .
[15]	吴倩, 高庆平, 单彬, 王文政, 齐玉萍, 台夕市, 王霞, 郑冬冬, 严虹, 应斌武, 罗永嵩, 孙圣钧, 刘倩, Hamdy Mohamed S., 孙旭平. 自支撑过渡金属海水电解析氧催化剂研究进展[J]. 物理化学学报, 2023, 39(12): 2303012 - .

NiS-Ni₃S₂树状异质结阵列在析氧反应中的应用

Tree-Like NiS-Ni₃S₂/NF Heterostructure Array and Its Application in Oxygen Evolution Reaction

RichHTML

PDF

赞

可视化

摘要/Abstract

支持信息

引用本文

使用本文

参考文献

相关文章 15

Metrics

推荐阅读 0